Effects of micro-arc oxidation on the corrosion behaviors of magnesium alloy Mg-8.0Al-1.0Zn-1.0La

L. Lei, M. Biao, Li Qiang, Huang Guojie
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Abstract

Magnesium alloys attract more and more attentions in the field of biomaterials because of their favorable biocompatibility and biodegradable properties. Presently, the bottleneck of application of magnesium alloys as biomaterials is that their corrosion speed is too rapid. The magnesium alloy will seriously erode before the tissue or organ recovers. Moreover, the excessive hydrogen gas that cannot be processed by human body will generate in the corrosion process. Therefore, improving the corrosion resistance is the key to successfully apply magnesium alloys in the field of biomaterials. In present, magnesium alloy Mg-8.0Al-1.0Zn-1.0La fabricated by authors in prior research was processed by micro-arc oxidation technology for improving the corrosion resistance. Results showed that the anodic polarization behavior transferred from the active dissolution to the self-passivation after micro-arc oxidation. The self corrosion current density decreased 3∼5 order of magnitude. The micro-arc oxidation film generated in-situ on the surface of Mg-8.0Al-1.0Zn-1.0La alloy constitutes of ceramic materials, such as MgO, MgSiO3, Mg2SiO4 and Al2O3. The ceramic film can protected the magnesium matrix from eroding.
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微弧氧化对Mg-8.0Al-1.0Zn-1.0La镁合金腐蚀行为的影响
镁合金以其良好的生物相容性和生物可降解性在生物材料领域受到越来越多的关注。目前,镁合金作为生物材料应用的瓶颈是其腐蚀速度过快。在组织或器官恢复之前,镁合金会严重腐蚀。此外,在腐蚀过程中还会产生人体无法处理的过量氢气。因此,提高镁合金的耐腐蚀性能是镁合金在生物材料领域成功应用的关键。目前,为了提高镁合金的耐蚀性,采用微弧氧化技术制备了Mg-8.0Al-1.0Zn-1.0La镁合金。结果表明,微弧氧化后的阳极极化行为由活性溶解转变为自钝化。自腐蚀电流密度降低3 ~ 5个数量级。在Mg-8.0Al-1.0Zn-1.0La合金表面原位生成的微弧氧化膜由MgO、MgSiO3、Mg2SiO4和Al2O3等陶瓷材料组成。陶瓷膜可以保护镁基体不受侵蚀。
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