New Access to Nano[Mn]-Pyranopyrazole[2,3-c]dichloride Series As a Nano-Structured Schiff-Base Complex

IF 0.6 4区 综合性期刊 Q3 MULTIDISCIPLINARY SCIENCES Chiang Mai Journal of Science Pub Date : 2023-03-31 DOI:10.12982/cmjs.2023.017
M. F. Mohammat, F. E. Bouchamma, Fatin Nur Ain Abdul Rashid, Muhammad Siddiq Maarop, Mohd Abdul Fatah Abdul Manan
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Abstract

A series of novel nano-structured manganese pyranopyrazole Schiff base complex (3a-l) has been synthesized and described. This synthetic complexation involved sequential reactions of domino four-component one-pot reaction for the template of pyranopyrazole (1), imination reaction (2) and finally completed by the complexation reaction with manganese to furnish the title compounds (3a-l). The salient of this nano-Schiff base synthetic reaction protocol is that diverse chemical functionalities were successfully incorporated, simple reaction protocol, and easy workup procedure to yield the title compounds from reasonable to moderate yield. All synthesized compounds were characterized by means of NMR, FTIR, EDX, and elemental analyzer, and by comparing the acquired spectra with the literature precedent for different manganese complexes. These findings revealed that the pyranopyrazole derivatives were successfully complexed with manganese to generate nano-Mn-Schiff base compounds. Further complexation of these derivatives generated 12 novel types of the title compounds (3a-l), which can then be subjected for future chemical applications.
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纳米[Mn]-吡喃吡唑[2,3-c]二氯代纳米结构席夫碱配合物的新途径
合成并描述了一系列新型纳米结构吡喃吡唑锰希夫碱配合物(3a-l)。该合成络合过程包括以吡喃吡唑为模板物的多米诺四组分一锅反应(1),模拟反应(2),最后与锰络合反应生成目标化合物(3a-l)的顺序反应。该纳米希夫碱合成反应方案的突出之处是成功地结合了多种化学官能团,反应方案简单,后处理步骤容易,从而得到了从合理到中等产率的目标化合物。通过NMR、FTIR、EDX和元素分析仪对合成的化合物进行了表征,并与文献中不同锰配合物的光谱进行了比较。这些发现表明吡喃吡唑衍生物成功地与锰络合生成纳米mn -希夫碱化合物。这些衍生物的进一步络合产生了12种新型的标题化合物(3a-l),这些化合物可以在未来的化学应用中使用。
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来源期刊
Chiang Mai Journal of Science
Chiang Mai Journal of Science MULTIDISCIPLINARY SCIENCES-
CiteScore
1.00
自引率
25.00%
发文量
103
审稿时长
3 months
期刊介绍: The Chiang Mai Journal of Science is an international English language peer-reviewed journal which is published in open access electronic format 6 times a year in January, March, May, July, September and November by the Faculty of Science, Chiang Mai University. Manuscripts in most areas of science are welcomed except in areas such as agriculture, engineering and medical science which are outside the scope of the Journal. Currently, we focus on manuscripts in biology, chemistry, physics, materials science and environmental science. Papers in mathematics statistics and computer science are also included but should be of an applied nature rather than purely theoretical. Manuscripts describing experiments on humans or animals are required to provide proof that all experiments have been carried out according to the ethical regulations of the respective institutional and/or governmental authorities and this should be clearly stated in the manuscript itself. The Editor reserves the right to reject manuscripts that fail to do so.
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