Effects of PEG on the stability and electrochemical properties of PEDOT: PSS films obtained by spin coating

A. Stoian, C. Pȋrvu, I. Demetrescu
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Abstract

By mixing the same concentration polyethylene glycol (PEG) with molar masses of 400, 600 and 1000, a series of poly (3,4-ethylenedioxythiophene):poly (styrenesulfonate) (PEDOT: PSS) composite thin films were prepared by spin coating. The morphology of the films was inspected by Atomic Force Microscopy (AFM). Electrochemical characterizations performed over a time span of five days including Cyclic Voltammetry (CV) and Electrochemical Impedance Spectroscopy (EIS) were used to determine the stability of the films. The experimental results showed that the properties of PEDOT: PSS films were greatly influenced by the molecular weight of PEG.
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聚乙二醇对旋涂法制备PEDOT: PSS薄膜稳定性和电化学性能的影响
将摩尔质量分别为400、600和1000的聚乙二醇(PEG)混合在一起,采用自旋涂覆法制备了一系列聚3,4-乙烯二氧噻吩-聚苯乙烯磺酸(PEDOT: PSS)复合薄膜。用原子力显微镜(AFM)观察了膜的形貌。在5天的时间内进行了电化学表征,包括循环伏安法(CV)和电化学阻抗谱法(EIS)来确定膜的稳定性。实验结果表明,PEG的分子量对PEDOT: PSS薄膜的性能有很大影响。
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