Plasma-Engineered Silica Acid Catalysts for Coffee Waste Conversion to Xylose

Sungho Lee, Qin Lusha, O. Li
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Abstract

s Recently, the need for next-generation energy sources to replace fossil energy is increasing rapidly due to various problems such as depletion of oil and generation of carbon dioxide. One alternative to this is coffee grounds, one of the substances being studied. Coffee is consumed a lot around the world, but the disposal of the grounds is a big problem. However, this coffee grounds can be used as a raw material for biodiesel because it is made of various organic compounds such as cellulose and hemicellulose. The most common process to make biodiesel is the process using concentrated sulfuric acid as homogeneous catalysts to break down coffee into monosaccharides. However, the corrosive nature and disposal problem create environmental concerns in this process. Recently, heterogeneous silica acid catalyst, attracts many attention due to its environmental friendly nature, low cost and recyclability. In this experiment, instead of the sol-gel method for preparing a conventional silica acid catalyst, we prepared silica acid catalyst using a plasma method that can improve the catalytic performance. In the case of using the plasma method, the specific surface area increased and the catalyst performance increased, which led to an increase in xylose conversion and selectivity of 6% and 4%, respectively.
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等离子体工程硅酸催化剂用于咖啡废弃物转化为木糖
最近,由于石油的枯竭和二氧化碳的产生等各种问题,对替代化石能源的下一代能源的需求正在迅速增加。另一种选择是咖啡渣,这是一种正在研究的物质。世界各地的咖啡消费量很大,但咖啡渣的处理是一个大问题。然而,这种咖啡渣可以作为生物柴油的原料,因为它是由各种有机化合物,如纤维素和半纤维素制成的。生产生物柴油最常见的方法是使用浓硫酸作为均相催化剂将咖啡分解成单糖。然而,在这个过程中,腐蚀性和处理问题引起了环境问题。近年来,多相硅酸催化剂因其环保、低成本和可回收性而受到广泛关注。在本次实验中,我们采用等离子体法制备硅酸催化剂,代替了传统的溶胶-凝胶法制备硅酸催化剂,从而提高了催化性能。采用等离子体法时,比表面积增大,催化剂性能提高,木糖转化率和选择性分别提高6%和4%。
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