Solubility of CO2 in Brine and Reservoir Oil for Depleted Reservoirs in China

Ke Zhang, D. Ma, Shi Li, Xinglong Chen
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Abstract

Many countries play an important role to carbon capture, utilization, and Storage (CCUS) to reduce emission. Geological storage is an important approach to cope with climate change. Live oil combined with saline aquifers and gas reservoirs are among the candidates for carbon dioxide (CO 2 ) sequestration, owing to their proven sealing capabilities and characterization. CO 2 mainly from power industrial was captured to improve oil recovery in some oilfields in China, and solubility is a key factor to evaluate storage ability of reservoir and saline aquifer. In this paper, CO 2 sequestration mechanisms in deplete reservoir and saline aquifer were explained. An experimental method to test solubility of CO 2 in emulsion system of liver oil and brine was developed. The experimental results showed that with the salinity increased, the solubility of CO 2 in reservoir oil increased slightly, and the solubility of CO 2 in brine decreased. Salinity has little impact on solubility of CO 2 in reservoir oil. With the pressure increased, the solubility of CO 2 in reservoir oil and brine both increased. Molecular diameter of reservoir oil and white oil have inverse proportion relationship with the solubility Research on solubility of CO 2 in brine and reservoir oil for depleted reservoir in China enabled us to better predict and deal with the challenges for rapid development of carbon storage.
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中国衰竭油藏CO2在盐水和油藏油中的溶解度
许多国家在碳捕集、利用与封存(CCUS)方面发挥着重要作用。地质封存是应对气候变化的重要手段。由于已证实的密封能力和特性,与含盐含水层和气藏结合的活油是二氧化碳(co2)封存的候选者。中国部分油田主要捕集来自电力工业的CO 2以提高采收率,溶解度是评价储层和咸水层储集能力的关键因素。本文阐述了枯竭层和含盐层的co2固存机制。提出了一种测定co2在鱼肝油-卤水乳化体系中溶解度的实验方法。实验结果表明,随着矿化度的升高,co2在储层油中的溶解度略有升高,而在盐水中的溶解度下降。盐度对co2在储层油中的溶解度影响不大。随着压力的增大,co2在油藏油和盐水中的溶解度均增大。储层油和白油的分子直径与溶解度成反比关系研究中国衰竭油藏co2在盐水和储层油中的溶解度,可以更好地预测和应对储碳快速发展的挑战。
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