The Need of NMR Cement Properties Characterization and Lesson Learned

A. Ichim, Fatemeh K. Saleh, C. Teodoriu, C. Sondergeld
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引用次数: 1

Abstract

Cement is a key element for successful drilling and completing of a well. From oil and gas wells to geothermal applications, cement is a major material ensuring zonal isolation. With an increase in global energy needs and an expected uptick in drilling and plugging and abandonment activities, evaluating and understanding cement properties is crucial, since these properties are used in various engineering designs and calculations. The objective of this paper is to present how Nuclear Magnetic Resonance (NMR) can be used to understand the cement hydration process and the development of key properties such as strength and porosity. NMR applications for cement include determination of porosity, water interactions, identification of hydration stages and C-S-H gel development with curing time. Since water is present in all cement slurries, NMR can potentially help to understand microstructural changes in cement during curing. Data from more than 600 cement specimens cured for more than a year are compiled. Standard cement properties such as UCS (unconfined compressive strength) are compared with NMR responses. In this paper, we document cement hydration and porosity changes through NMR measurements in samples with five different recipes. Our study also confirms a strong correlation between NMR response and cement strength.
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核磁共振水泥性能表征的必要性及经验教训
水泥是成功钻完井的关键因素。从油气井到地热应用,水泥是确保层间隔离的主要材料。随着全球能源需求的增加以及钻井、封堵和弃井活动的预期增加,评估和了解水泥的性能至关重要,因为这些性能将用于各种工程设计和计算。本文的目的是介绍如何使用核磁共振(NMR)来了解水泥水化过程以及强度和孔隙率等关键性能的发展。核磁共振在水泥中的应用包括孔隙度的测定、水的相互作用、水化阶段的鉴定以及C-S-H凝胶随固化时间的发展。由于水存在于所有水泥浆中,因此核磁共振可以潜在地帮助了解水泥在养护过程中的微观结构变化。数据来自600多个固化一年以上的水泥试件。标准水泥性能如UCS(无侧限抗压强度)与核磁共振响应进行了比较。在本文中,我们通过核磁共振测量记录了五种不同配方样品的水泥水化和孔隙度变化。我们的研究也证实了核磁共振响应和水泥强度之间的强相关性。
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