Recent advance on cobalt-based oxide catalyst for the catalytic removal of volatile organic compounds: A review

Xi Chen , Shinong Yu , Wei Liu , Shuning Zhang , Shuchen Liu , Yang Feng , Xuejun Zhang
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引用次数: 9

Abstract

As the main contributor to air pollution, lots of volatile organic compounds (VOCs) were emitted into the atmosphere due to the rapid urbanization and industrialization, threatening environmental safety and human health. Catalytic oxidation has been verified as an efficient approach for VOCs elimination from industrial waste gas streams. Owing to the merits of cost-effective and high activity, cobalt-based catalysts have been considered as one of the most promising candidates for VOCs degradation. This review systematically summarized the developments achieved in the design of cobalt-based catalysts for VOCs removal over the past decade. Specifically, the fabrication of single cobalt oxides, cobalt-based binary oxides and cobalt-based composites, as well as the modified cobalt-based oxides by the surface engineering strategies, such as doping technology and acid etching method are coherently reviewed. Subsequently, the corresponding kinetic models and mechanisms are also discussed. Finally, considering the enormous challenges and opportunities in this field, the perspective with respect to future research on cobalt-based catalysts is proposed.

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钴基氧化物催化剂催化脱除挥发性有机物的研究进展
随着城市化和工业化进程的加快,大量挥发性有机化合物(VOCs)被排放到大气中,威胁着环境安全和人类健康。催化氧化是消除工业废气中挥发性有机化合物的一种有效方法。钴基催化剂由于具有高性价比和高活性的优点,已被认为是降解挥发性有机化合物最有前途的候选材料之一。本文系统地总结了近十年来钴基催化剂在去除VOCs方面的研究进展。具体地,综述了单钴氧化物、钴基二元氧化物和钴基复合材料的制备,以及采用掺杂技术和酸蚀法等表面工程策略对钴基氧化物进行改性的研究进展。随后,讨论了相应的动力学模型和机理。最后,考虑到该领域面临的巨大挑战和机遇,对钴基催化剂的未来研究提出了展望。
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Outside Front Cover Table of Contents Outside Back Cover On controllability of fluidized bed reduction of iron ore by CH4 for selective formation of magnetite Organics-based Aqueous Batteries: Concept for Stationary Energy Storage with Resource Feasibility
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