Influence of non-thermal plasma pretreatment on viscous crude oil wastewater evaporation process and on quality of the distilled water

Yi Zhang, Dezhen Chen, L. Zou, Yan-Meng Bi, Jiacai Xie
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引用次数: 2

Abstract

To recycle viscous crude oil wastewater through evaporation to supply feeding water for steam injection boiler is a promising technology to benefit viscous crude oil extraction. In order to improve quality of distilled water and avoid scale formation during the evaporation process, the technology of non-thermal plasma (NTP) was tried in this research to pre-treat viscous crude oil wastewater before evaporation. Firstly the wastewater was sprayed into NTP reactor tube and then sent to the evaporator. It was found that after pretreatment, the contents of SiO2 and hardness of pretreated wastewater were reduced. Accordingly, distilled water from evaporating the pretreated wastewater was corresponded to lower hardness and decreased conductivity. The SiO2 contents in distilled water were changed without obvious rules. However as comparing the quality of distilled water from the pretreated wastewater with that from common evaporation facilities, it can be found that the quality of distilled water from NTP treated samples was better except that its hardness is higher which was caused by foam carrying for foam remover was not available in the experimental evaporation system. Low-temperature plasma, as a pretreatment technology, also hindered hard scale formation on the heating surface of evaporator and it is possible to replace scale formation chemicals in operation, providing an economical and energy-saving way for recovering wastewater water.
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非热等离子体预处理对稠油废水蒸发过程及蒸馏水质量的影响
利用蒸发法回收稠油废水为注汽锅炉提供给水是一项很有前途的稠油开采技术。为了提高蒸馏水的质量,避免蒸馏水在蒸发过程中结垢,本研究采用非热等离子体(NTP)技术对稠油废水进行蒸发前预处理。废水先喷入NTP反应器管,再送入蒸发器。结果表明,预处理后废水的SiO2含量和硬度均有所降低。因此,预处理废水蒸发后的蒸馏水硬度降低,电导率降低。蒸馏水中SiO2含量变化无明显规律。然而,通过将预处理废水蒸馏水的质量与普通蒸发设备蒸馏水的质量进行比较,可以发现NTP处理后的样品蒸馏水质量较好,但其硬度较高,这是由于实验蒸发系统中没有泡沫去除剂的泡沫携带造成的。低温等离子体作为一种预处理技术,也阻碍了蒸发器受热面上硬垢的形成,在运行中可以替代结垢剂,为废水的回收提供了一种经济、节能的途径。
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