Antibacterial Properties of Polyurethane / Benzalkonium Chloride Nanofibers

Ayşe Arslan
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Abstract

The textile sector brings us different functional features besides our need for dressing. One of them is to give antibacterial properties to textile structures. Antibacterial property increases the quality of life by protecting people against bacterial attacks. It is possible to achieve antibacterial activity at different stages of textile production processes. One of these processes is the electrospinning method, which makes it possible to add antibacterial substances into a polymer containing solution to be processed to a nanofiber structure. In this study, nanofiber structures were obtained by electrospinning from polyurethane (PU)/benzalkonium chloride (BAC) solutions at different concentrations. Then, their morphological, mechanical and antibacterial characteristics were investigated. According to the results, the produced fiber membranes had nanometer size. The nanofiber surfaces were intensive and uniform when BAC concentration was 0.5% and 1.0%. But, the uniformity lost at the higher BAC concentrations. The thinnest fiber diameter of nanofibers was 423±80nm. The strongest (6,42MPa) nanofiber structure was observed when the electrospinning solution included 0.98% PU and 1% BAC. The antibacterial activities of the fabrics were tested against gram-negative ( E. coli and P. aeruginosa ) and gram-positive ( B. subtilis and S. aureus ) bacteria. The fabrics showed antibacterial activity with a dose dependent manner against all the tested bacteria by the order of B. subtilis  >  S. aureus  >  E. coli  >  P. aeruginosa .
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聚氨酯/苯扎氯铵纳米纤维的抗菌性能
纺织行业给我们带来了不同的功能特点,除了我们对着装的需要。其中之一是赋予纺织结构抗菌性能。抗菌特性通过保护人们免受细菌攻击来提高生活质量。它可以在纺织品生产过程的不同阶段实现抗菌活性。其中一种方法是静电纺丝法,它可以将抗菌物质添加到含有聚合物的溶液中,然后加工成纳米纤维结构。以不同浓度的聚氨酯(PU)/苯扎氯铵(BAC)溶液为原料,采用静电纺丝法制备了纳米纤维结构。然后,研究了它们的形态、力学和抗菌特性。结果表明,制备的纤维膜具有纳米级的尺寸。BAC浓度为0.5%和1.0%时,纳米纤维表面致密均匀。但是,在较高的BAC浓度下,均匀性丧失。纳米纤维的最细纤维直径为423±80nm。当静电纺丝溶液中PU含量为0.98%,BAC含量为1%时,纳米纤维结构强度为6,42 mpa。测定了织物对革兰氏阴性菌(大肠杆菌和铜绿假单胞菌)和革兰氏阳性菌(枯草芽孢杆菌和金黄色葡萄球菌)的抑菌活性。织物对所有细菌的抑菌活性表现为枯草芽孢杆菌>金黄色葡萄球菌>大肠杆菌>铜绿假单胞菌。
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Elektro Çekim Yöntemi ile Çörek Otu ve Yün Yağı Takviyeli Yara Örtüsü Geliştirilmesi Investigation of Water Permeability of Ultrasonic Seaming on PU Coated Fabrics Nikel Alaşımlarının Farklı Soğutma/Yağlama Koşulları Altında Talaşlı İmalatının Kesme Kuvvetlerine Etkisi: Bir Derleme Çalışması Antibacterial Properties of Polyurethane / Benzalkonium Chloride Nanofibers Effects of Carbon Nanotube-Phosphorus Based Flame Retardant Combinations on Flammability of Polypropylene
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