Peculiarities of Dipolar Ordering in Mixed Cation Halide Perovskites

M. Šimėnas, S. Balčiu̅nas, Š. Svirskas, M. Kinka, V. Samulionis, R. Grigalaitis, J. Banys, A. Gągor, M. Ma̧czka, A. Garbaras, A. Sieradzki
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Abstract

Here, we present a multitechnique experimental study of structural phase transitions and dipolar dynamics in the novel mixed methylammonium (MA)/dimethylammonium (DMA) MA1-xDMAxPbBr3 hybrid perovskites. The obtained results demonstrate a suppression of the structural phase transitions and stabilization of the cubic phase even for a small amount of DMA cations. For high DMA concentration, we observe a disappearance of the structural phase transitions and emergence of a glassy phase of electric dipoles.
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混合阳离子卤化钙钛矿偶极序的特殊性
本文采用多技术实验研究了新型混合甲基铵(MA)/二甲铵(DMA) MA1-xDMAxPbBr3杂化钙钛矿的结构相变和偶极动力学。所得结果表明,即使少量的DMA阳离子也能抑制结构相变和稳定立方相。对于高浓度的DMA,我们观察到结构相变的消失和电偶极子玻璃相的出现。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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