Autoclave modeling of corrosion processes occurring in a gas pipeline during transportation of an unprepared multiphase medium containing CO2

IF 2.4 Q2 MINING & MINERAL PROCESSING Journal of Mining Institute Pub Date : 2022-12-30 DOI:10.31897/pmi.2022.92
N. Shaposhnikov, I. Golubev, S. Khorobrov, Alexander Kolotiy, A. Ioffe, V. Revyakin
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Abstract

The problem of selecting a method for ensuring the reliability of the unprepared fluid transport facilities of an unprepared fluid in the presence of carbon dioxide is considered. Carbon dioxide corrosion is one of the dangerous types of damage to field and main pipelines. It has been shown that dynamic autoclave tests should be carried out during staged laboratory tests in order to determine the intensity of carbon dioxide corrosion and to select the optimal method of protection. A hypothesis about the imperfection of the existing generally accepted approaches to dynamic corrosion testing has been put forward and confirmed. A test procedure based on the use of an autoclave with an overhead stirrer, developed using elements of mathematical modeling, is proposed. The flows created in the autoclave provide corrosive wear of the sample surface similar to the internal surfaces elements wear of the pipelines piping of gas condensate wells. The autoclave makes it possible to simulate the effect of the organic phase on the flow rate and the nature of corrosion damage to the metal surface, as well as the effect of the stirrer rotation speed and, accordingly, the shear stress of the cross section on the corrosion rate in the presence/absence of a corrosion inhibitor. The given results of staged tests make it possible to judge the high efficiency of the developed test procedure.
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高压灭菌器模拟含CO2的未准备多相介质在输气管道中发生的腐蚀过程
考虑了在存在二氧化碳的情况下,选择一种方法来保证未准备流体的未准备流体输送设施的可靠性的问题。二氧化碳腐蚀是油田和主要管道的危险破坏类型之一。为了确定二氧化碳腐蚀的强度和选择最佳的保护方法,应在分阶段的实验室试验中进行动态高压灭菌器试验。提出并证实了现有普遍接受的动态腐蚀试验方法的不完全性。提出了一种基于使用带有顶置搅拌器的高压灭菌器的测试程序,并利用数学建模的元素进行了开发。在高压灭菌器中产生的流动对样品表面造成腐蚀性磨损,类似于凝析气井管道的内部表面元件磨损。高压灭菌器可以模拟有机相对流速的影响和金属表面腐蚀损伤的性质,以及搅拌器转速的影响,相应地,在存在/不存在缓蚀剂的情况下,截面的剪切应力对腐蚀速率的影响。阶段测试的给定结果可以判断所开发的测试程序的高效率。
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来源期刊
Journal of Mining Institute
Journal of Mining Institute MINING & MINERAL PROCESSING-
CiteScore
7.50
自引率
25.00%
发文量
62
审稿时长
8 weeks
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