I. Indrupskiy, I. Ibragimov, T. Tsagan-Mandzhiev, A. Lutfullin, A. Chirkunov, R. Shakirov, Yu.V. Alekseeva
Results are discussed for evaluation of effectiveness of the cyclic geomechanical treatment (CGT) on a Tournaisian carbonate reservoir. Analysis of laboratory experiments performed according to a special program to assess permeability changes for Tournaisian samples under cyclic changes in pore pressure is presented. The main conclusion is the positive selectivity of the CGT: an increase in permeability is observed for samples saturated with hydrocarbons (kerosene) with connate water, and maximal effect is related to the tightest samples. For water-saturated samples, the permeability decreases after the CGT. Thus, the CGT improves the drainage conditions for tight oil-saturated intervals. It is also confirmed that the CGT reduces the fracturing pressure in carbonate reservoirs. Using flow simulations on detailed sector models taking into account the results of laboratory experiments, a possible increase in well productivity index after CGT with different amplitudes of pressure variation was estimated. Results of a pilot CGT study on a well operating a Tournaisian carbonate reservoir are presented, including the interpretation of production logging and well testing. The increase in the well productivity index is estimated at 44-49 % for liquid and at 21-26 % for oil, with a more uniform inflow profile after the treatment. The results of the field experiment confirm the conclusions about the mechanisms and features of the CGT obtained from laboratory studies and flow simulations.
{"title":"Laboratory, numerical and field assessment of the effectiveness of cyclic geomechanical treatment on a tournaisian carbonate reservoir","authors":"I. Indrupskiy, I. Ibragimov, T. Tsagan-Mandzhiev, A. Lutfullin, A. Chirkunov, R. Shakirov, Yu.V. Alekseeva","doi":"10.31897/pmi.2023.5","DOIUrl":"https://doi.org/10.31897/pmi.2023.5","url":null,"abstract":"Results are discussed for evaluation of effectiveness of the cyclic geomechanical treatment (CGT) on a Tournaisian carbonate reservoir. Analysis of laboratory experiments performed according to a special program to assess permeability changes for Tournaisian samples under cyclic changes in pore pressure is presented. The main conclusion is the positive selectivity of the CGT: an increase in permeability is observed for samples saturated with hydrocarbons (kerosene) with connate water, and maximal effect is related to the tightest samples. For water-saturated samples, the permeability decreases after the CGT. Thus, the CGT improves the drainage conditions for tight oil-saturated intervals. It is also confirmed that the CGT reduces the fracturing pressure in carbonate reservoirs. Using flow simulations on detailed sector models taking into account the results of laboratory experiments, a possible increase in well productivity index after CGT with different amplitudes of pressure variation was estimated. Results of a pilot CGT study on a well operating a Tournaisian carbonate reservoir are presented, including the interpretation of production logging and well testing. The increase in the well productivity index is estimated at 44-49 % for liquid and at 21-26 % for oil, with a more uniform inflow profile after the treatment. The results of the field experiment confirm the conclusions about the mechanisms and features of the CGT obtained from laboratory studies and flow simulations.","PeriodicalId":16398,"journal":{"name":"Journal of Mining Institute","volume":"67 1","pages":""},"PeriodicalIF":2.0,"publicationDate":"2023-05-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86111027","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The paper investigates the harmonic impedance determination of the power supply system of a mining enterprise. This parameter is important when calculating modes with voltage distortions, since the determined parameters of harmonic currents and voltages significantly depend on its value, which allow the most accurate modeling of processes in the presence of distortions in voltage and current. The power supply system of subsurface mining is considered, which is characterized by a significant branching of the electrical network and the presence of powerful nonlinear loads leading to a decrease in the power quality at a production site. The modernization of the mining process, the integration of automated electrical drive systems, renewable energy sources, energy-saving technologies lead to an increase in the energy efficiency of production, but also to a decrease in the power quality, in particular, to an increase in the level of voltage harmonics. The problem of determining the grid harmonic impedance is solved in order to improve the quality of design and operation of power supply systems for mining enterprises, taking into account the peculiarities of their workload in the extraction of solid minerals by underground method. The paper considers the possibility of determining the grid impedance based on the measurement of non-characteristic harmonics generated by a special nonlinear load. A thyristor power controller based on phase regulation of the output voltage is considered as such a load. Simulation computer modeling and experimental studies on a laboratory test bench are used to confirm the proposed method. The recommendations for selecting load parameters and measuring device connection nodes have been developed.
{"title":"Determination of the grid impedance in power consumption modes with harmonics","authors":"A. Skamyin, V. Dobush, M. Jopri","doi":"10.31897/pmi.2023.25","DOIUrl":"https://doi.org/10.31897/pmi.2023.25","url":null,"abstract":"The paper investigates the harmonic impedance determination of the power supply system of a mining enterprise. This parameter is important when calculating modes with voltage distortions, since the determined parameters of harmonic currents and voltages significantly depend on its value, which allow the most accurate modeling of processes in the presence of distortions in voltage and current. The power supply system of subsurface mining is considered, which is characterized by a significant branching of the electrical network and the presence of powerful nonlinear loads leading to a decrease in the power quality at a production site. The modernization of the mining process, the integration of automated electrical drive systems, renewable energy sources, energy-saving technologies lead to an increase in the energy efficiency of production, but also to a decrease in the power quality, in particular, to an increase in the level of voltage harmonics. The problem of determining the grid harmonic impedance is solved in order to improve the quality of design and operation of power supply systems for mining enterprises, taking into account the peculiarities of their workload in the extraction of solid minerals by underground method. The paper considers the possibility of determining the grid impedance based on the measurement of non-characteristic harmonics generated by a special nonlinear load. A thyristor power controller based on phase regulation of the output voltage is considered as such a load. Simulation computer modeling and experimental studies on a laboratory test bench are used to confirm the proposed method. The recommendations for selecting load parameters and measuring device connection nodes have been developed.","PeriodicalId":16398,"journal":{"name":"Journal of Mining Institute","volume":"52 1","pages":""},"PeriodicalIF":2.0,"publicationDate":"2023-05-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80197324","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
O. Cheremisina, M. Ponomareva, Anastasia Molotilova, Yulia Mashukova, M. Soloviev
Obtaining and production of metals from natural raw materials causes a large amount of liquid, solid, and gaseous wastes of various hazard classes that have a negative impact on the environment. In the production of titanium dioxide from ilmenite concentrate, hydrolytic sulphuric acid is formed, which includes various metal cations, their main part is iron (III) and titanium (IV) cations. Hydrolytic acid waste is sent to acid storage facilities, which have a high environmental load. The article describes the technology of ion exchange wastewater treatment of acid storage facility from iron (III) and titanium (IV) cations, which form compounds with sulphate ions and components of organic waste in acidic environments. These compounds are subjected to dispersion and dust loss during the evaporation of a water technogenic facility, especially in summer season. Sorption of complex iron (III) cations [FeSO4]+ and titanyl cations TiO2+ from sulphuric acid solutions on cation exchange resins KU-2-8, Puromet MTS9580, and Puromet MTS9560 was studied. Sorption isotherms were obtained both for individual [FeSO4]+ and TiO2+ cations and in the joint presence. The values of the equilibrium constants at a temperature of 298 K and the changes in the Gibbs energy are estimated. The capacitive characteristics of the sorbent were determined for individual cations and in the joint presence.
{"title":"Sorption purification of acid storage facility water from iron and titanium on organic polymeric materials","authors":"O. Cheremisina, M. Ponomareva, Anastasia Molotilova, Yulia Mashukova, M. Soloviev","doi":"10.31897/pmi.2023.28","DOIUrl":"https://doi.org/10.31897/pmi.2023.28","url":null,"abstract":"Obtaining and production of metals from natural raw materials causes a large amount of liquid, solid, and gaseous wastes of various hazard classes that have a negative impact on the environment. In the production of titanium dioxide from ilmenite concentrate, hydrolytic sulphuric acid is formed, which includes various metal cations, their main part is iron (III) and titanium (IV) cations. Hydrolytic acid waste is sent to acid storage facilities, which have a high environmental load. The article describes the technology of ion exchange wastewater treatment of acid storage facility from iron (III) and titanium (IV) cations, which form compounds with sulphate ions and components of organic waste in acidic environments. These compounds are subjected to dispersion and dust loss during the evaporation of a water technogenic facility, especially in summer season. Sorption of complex iron (III) cations [FeSO4]+ and titanyl cations TiO2+ from sulphuric acid solutions on cation exchange resins KU-2-8, Puromet MTS9580, and Puromet MTS9560 was studied. Sorption isotherms were obtained both for individual [FeSO4]+ and TiO2+ cations and in the joint presence. The values of the equilibrium constants at a temperature of 298 K and the changes in the Gibbs energy are estimated. The capacitive characteristics of the sorbent were determined for individual cations and in the joint presence.","PeriodicalId":16398,"journal":{"name":"Journal of Mining Institute","volume":"109 1","pages":""},"PeriodicalIF":2.0,"publicationDate":"2023-05-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80769230","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
In the composition of tantalum-niobates the tin-bearing wodginite group minerals (WGM) were found: wod-ginite, titanowodginite, ferrowodginite, ferrotitanowodginite, lithiowodginite, tantalowodginite, “wolframowodginite”. We reviewed the worldwide research on WGM and created a database of 698 analyses from 55 sources including the author's data. WGM are associated with Li-F pegmatites and Li-F granites. Wodginite is the most prevalent mineral, occurring in 86.6 % of pegmatites and 78.3 % of granites. The occurrence of WGM in granites and pegmatites differs. For instance, titanowodginite and “wolframowodginite” occur three times more frequently in granites than in pegmatites, whereas lithiowodginite and tantalowodginite do not appear in granites at all. The difference between WGM in granites and pegmatites is in finer grain size, higher content of Sn, Nb, Ti, W, and Sc; lower content of Fe3+, Ta, Zr, Hf; higher ratio of Mn/(Mn + Fe); and lower ratio of Zr/Hf. The evolutionary series of WGM in pegmatites are as follows: ferrowodginite → ferrotitanowodginite → titanowodginite → “wolframowodginite” → wodginite → tantalowodginite; in granites: ferrowodginite → ferrotitanowodginite → “wolframowodginite” → wodginite → titanowodginite. WGM can serve as indicators of tantalum-bearing pegmatites and granites. In Russia the promising sources of tantalum are deposits of the Far Eastern belt of Li-F granites containing wodginite.
{"title":"Wodginite as an indicator mineral of tantalum-bearing pegmatites and granites","authors":"V. Alekseev","doi":"10.31897/pmi.2023.19","DOIUrl":"https://doi.org/10.31897/pmi.2023.19","url":null,"abstract":"In the composition of tantalum-niobates the tin-bearing wodginite group minerals (WGM) were found: wod-ginite, titanowodginite, ferrowodginite, ferrotitanowodginite, lithiowodginite, tantalowodginite, “wolframowodginite”. We reviewed the worldwide research on WGM and created a database of 698 analyses from 55 sources including the author's data. WGM are associated with Li-F pegmatites and Li-F granites. Wodginite is the most prevalent mineral, occurring in 86.6 % of pegmatites and 78.3 % of granites. The occurrence of WGM in granites and pegmatites differs. For instance, titanowodginite and “wolframowodginite” occur three times more frequently in granites than in pegmatites, whereas lithiowodginite and tantalowodginite do not appear in granites at all. The difference between WGM in granites and pegmatites is in finer grain size, higher content of Sn, Nb, Ti, W, and Sc; lower content of Fe3+, Ta, Zr, Hf; higher ratio of Mn/(Mn + Fe); and lower ratio of Zr/Hf. The evolutionary series of WGM in pegmatites are as follows: ferrowodginite → ferrotitanowodginite → titanowodginite → “wolframowodginite” → wodginite → tantalowodginite; in granites: ferrowodginite → ferrotitanowodginite → “wolframowodginite” → wodginite → titanowodginite. WGM can serve as indicators of tantalum-bearing pegmatites and granites. In Russia the promising sources of tantalum are deposits of the Far Eastern belt of Li-F granites containing wodginite.","PeriodicalId":16398,"journal":{"name":"Journal of Mining Institute","volume":"40 1","pages":""},"PeriodicalIF":2.0,"publicationDate":"2023-04-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84233501","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Vladimir Korshunov, Anton Pavlovich, Alexander Bazhukov
Experimental data on the relationship of the residual shear strength of rocks in closed cracks with the functional characteristics of intact rocks – the tensile and compressive components of adhesion, the roughness of the crack surfaces, and the level of normal stresses are presented. A unified integrated approach determines the shear strength of intact and destroyed rocks, the residual shear strength of closed rough cracks has been developed. The approach provides for the selection of stress intervals corresponding to different types of fracture, for each of which a strength criterion is proposed, expressed in terms of functional characteristics of intact rock. An express method for estimating the residual shear strength of rocks by cracks with a rough surface has been developed, in which an improved method of loading samples with spherical indentors is used as a basic test method. The express method implements the transition from the data of mechanical tests of samples with spherical indentors to the shear strength indicators for cracks in the rock mass, taking into account the level of normal stresses and the roughness of the crack surfaces measured in field conditions. In this case the roughness scale developed by Barton is used. The express method is informative and available in the fieldwork.
{"title":"Оценка сдвиговой прочности горных пород по трещинам на основе результатов испытаний образцов сферическими инденторами","authors":"Vladimir Korshunov, Anton Pavlovich, Alexander Bazhukov","doi":"10.31897/pmi.2023.16","DOIUrl":"https://doi.org/10.31897/pmi.2023.16","url":null,"abstract":"Experimental data on the relationship of the residual shear strength of rocks in closed cracks with the functional characteristics of intact rocks – the tensile and compressive components of adhesion, the roughness of the crack surfaces, and the level of normal stresses are presented. A unified integrated approach determines the shear strength of intact and destroyed rocks, the residual shear strength of closed rough cracks has been developed. The approach provides for the selection of stress intervals corresponding to different types of fracture, for each of which a strength criterion is proposed, expressed in terms of functional characteristics of intact rock. An express method for estimating the residual shear strength of rocks by cracks with a rough surface has been developed, in which an improved method of loading samples with spherical indentors is used as a basic test method. The express method implements the transition from the data of mechanical tests of samples with spherical indentors to the shear strength indicators for cracks in the rock mass, taking into account the level of normal stresses and the roughness of the crack surfaces measured in field conditions. In this case the roughness scale developed by Barton is used. The express method is informative and available in the fieldwork. \u0000 ","PeriodicalId":16398,"journal":{"name":"Journal of Mining Institute","volume":"48 1","pages":""},"PeriodicalIF":2.0,"publicationDate":"2023-04-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89642495","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Modern development vector of environmental monitoring leads to elaboration of analytical methods for qualitative and quantitative analysis of different ecotoxicants. Many studies face the lack of information on isomers and homologues of already studied compounds. This problem cannot always be solved experimentally due to the difficulty of separating or synthesizing certain compounds; the use of group theories of solutions will help partly; using them, solubility in water or partition coefficient between two immiscible solvents is calculated for ecotoxicants. These parameters are important for solving the analytical and ecological problems. The partition coefficient in the octanol – water system is associated with a possibility of accumulation of different compounds in living organisms; the partition coefficient in the hexane – acetonitrile system can be used in gas chromatographic analysis. Solubility in water is closely associated with accumulation of ecotoxicants in water bodies, as well as with their ability to be transferred. This paper presents the capabilities of the UNIFAC model for solving physicochemical problems using the example of calculating the properties of real ecotoxicants on the basis of the available thermodynamic data. All the obtained calculated values were compared with those determined experimentally. In the case of pyrene derivatives, solubility data were obtained for the first time using a correlation group model to calculate the heat of fusion and melting temperature.
{"title":"Применение модели UNIFAC в расчете физико-химических свойств экотоксикантов для технологических и экоаналитических целей","authors":"V. Povarov, I. Efimov","doi":"10.31897/pmi.2023.41","DOIUrl":"https://doi.org/10.31897/pmi.2023.41","url":null,"abstract":"Modern development vector of environmental monitoring leads to elaboration of analytical methods for qualitative and quantitative analysis of different ecotoxicants. Many studies face the lack of information on isomers and homologues of already studied compounds. This problem cannot always be solved experimentally due to the difficulty of separating or synthesizing certain compounds; the use of group theories of solutions will help partly; using them, solubility in water or partition coefficient between two immiscible solvents is calculated for ecotoxicants. These parameters are important for solving the analytical and ecological problems. The partition coefficient in the octanol – water system is associated with a possibility of accumulation of different compounds in living organisms; the partition coefficient in the hexane – acetonitrile system can be used in gas chromatographic analysis. Solubility in water is closely associated with accumulation of ecotoxicants in water bodies, as well as with their ability to be transferred. This paper presents the capabilities of the UNIFAC model for solving physicochemical problems using the example of calculating the properties of real ecotoxicants on the basis of the available thermodynamic data. All the obtained calculated values were compared with those determined experimentally. In the case of pyrene derivatives, solubility data were obtained for the first time using a correlation group model to calculate the heat of fusion and melting temperature.","PeriodicalId":16398,"journal":{"name":"Journal of Mining Institute","volume":"8 1","pages":""},"PeriodicalIF":2.0,"publicationDate":"2023-04-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81777995","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Mariya Pashkevich, Alexey Alekseenko, Ruslan Nureev
The mining industry is one of the most challenging in ensuring environmental safety. During the last century, the Karabash Copper Smelting Plant was processing sulfide ores and depositing the tailings into storage facilities that now occupy an area of more than 50 hectares. To date, abandoned tailings are a significant source of natural water, air, and soil pollution in the Karabash city district. The article comprehensively examines the environmental impact of the Karabashmed copper smelter, one of the oldest metallurgical enterprises in Russia. The effects of seepage from the two Karabashmed tailings facilities on water resources were assessed. We revealed that even outside the area of the direct impact of processing waste, the pH of natural water decreases to values 4-5. Further downstream, the infiltration water from the tailings pond No. 4 reduces the pH of river water to 3.0-3.5. The presented results of environmental engineering surveys are derived from sampling water and bottom sediments of the Ryzhiy Stream and the Sak-Elga River, sample preparation, and quantitative chemical analysis. The study revealed significant exceedances of the maximum permissible concentrations for a number of chemical elements in the impact zone of the copper ore processing tailings.
{"title":"Формирование экологического ущерба при складировании сульфидсодержащих отходов обогащения полезных ископаемых","authors":"Mariya Pashkevich, Alexey Alekseenko, Ruslan Nureev","doi":"10.31897/pmi.2023.32","DOIUrl":"https://doi.org/10.31897/pmi.2023.32","url":null,"abstract":"The mining industry is one of the most challenging in ensuring environmental safety. During the last century, the Karabash Copper Smelting Plant was processing sulfide ores and depositing the tailings into storage facilities that now occupy an area of more than 50 hectares. To date, abandoned tailings are a significant source of natural water, air, and soil pollution in the Karabash city district. The article comprehensively examines the environmental impact of the Karabashmed copper smelter, one of the oldest metallurgical enterprises in Russia. The effects of seepage from the two Karabashmed tailings facilities on water resources were assessed. We revealed that even outside the area of the direct impact of processing waste, the pH of natural water decreases to values 4-5. Further downstream, the infiltration water from the tailings pond No. 4 reduces the pH of river water to 3.0-3.5. The presented results of environmental engineering surveys are derived from sampling water and bottom sediments of the Ryzhiy Stream and the Sak-Elga River, sample preparation, and quantitative chemical analysis. The study revealed significant exceedances of the maximum permissible concentrations for a number of chemical elements in the impact zone of the copper ore processing tailings.","PeriodicalId":16398,"journal":{"name":"Journal of Mining Institute","volume":"43 1","pages":""},"PeriodicalIF":2.0,"publicationDate":"2023-04-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79888911","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
In this paper the problem of losses from evaporation of light fractions of hydrocarbons during loading operations of tanker fleets vessels is considered. It was found that there is no unified approach to modeling the system “tanker – gas phase pipeline – vapor recovery units” in open sources. The absence of a generally recognized model makes it impossible to scientifically justify the application of instruments to reducing losses and the development of corresponding measures. In work it is showed that the dynamics of growth of pressure in the inner tanker capacity is described by a differential equation, considering for non-stationary essence of the process. This equation is converted to a non-dimensional form and investigated in relation to the similarity criteria of this system. This research has allowed to establish unambiguously the general character of pressure changes in the inner tanker capacity, and to predict the peak values of its growth at the initial stage of the loading operation. The obtained equations were tested on real tanker loading data and showed satisfactory convergence with the experimental data. At different stages of the loading opera-tion the component composition of vapor changes, which is shown by chromatographic analysis of the gas mixture. With the availability of a model of hydrocarbon vapor displacement from the inner of tanker, it is possible to propose measures to minimize the negative impact on the environment and return valuable vapors of the product to the technological chain of transportation.
{"title":"Повышение эффективности систем улавливания паров нефти при товарно-транспортных операциях на нефтеналивных терминалах","authors":"Vladimir Pshenin, G. Zakirova","doi":"10.31897/pmi.2023.29","DOIUrl":"https://doi.org/10.31897/pmi.2023.29","url":null,"abstract":"In this paper the problem of losses from evaporation of light fractions of hydrocarbons during loading operations of tanker fleets vessels is considered. It was found that there is no unified approach to modeling the system “tanker – gas phase pipeline – vapor recovery units” in open sources. The absence of a generally recognized model makes it impossible to scientifically justify the application of instruments to reducing losses and the development of corresponding measures. In work it is showed that the dynamics of growth of pressure in the inner tanker capacity is described by a differential equation, considering for non-stationary essence of the process. This equation is converted to a non-dimensional form and investigated in relation to the similarity criteria of this system. This research has allowed to establish unambiguously the general character of pressure changes in the inner tanker capacity, and to predict the peak values of its growth at the initial stage of the loading operation. The obtained equations were tested on real tanker loading data and showed satisfactory convergence with the experimental data. At different stages of the loading opera-tion the component composition of vapor changes, which is shown by chromatographic analysis of the gas mixture. With the availability of a model of hydrocarbon vapor displacement from the inner of tanker, it is possible to propose measures to minimize the negative impact on the environment and return valuable vapors of the product to the technological chain of transportation.","PeriodicalId":16398,"journal":{"name":"Journal of Mining Institute","volume":"5 1","pages":""},"PeriodicalIF":2.0,"publicationDate":"2023-04-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72736942","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yana Legostaeva, Anna Gololobova, V. Popov, V. Makarov
Extraction of diamonds from primary deposits in Siberia is associated with the development of kimberlite pipes in challenging environmental conditions, accompanied by a complex impact on the environment. The article presents the results of monitoring the soil cover of the Nakyn kimberlite field in the Yakutia diamond province, which is affected by the facilities of the Nyurba Mining and Processing Division. Development of primary diamond deposits has a large-scale impact on the subsoil, topography, and soil cover: creation of the world's largest quarries, formation of dumps more than 100 m high, arrangement of extensive tailings, formation of solid and liquid industrial wastes of various chemical composition. The research is aimed at studying the spatial and temporal patterns of the technogenic impact on the soil cover, identifying the nature and level of transformation of the microelement composition of soils based on the analysis of the intra-profile and lateral distribution of mobile forms of trace elements. The study targets in 2007-2018 were zonal types of permafrost soils of northern taiga landscapes, cryozems, occupying 84 % of the total study area, which are characterized by biogenic accumulation of mobile forms of Ni, Mn, and Cd in the upper AO, Acr horizons, and Cr, Ni, Co, Mn, Cu in the suprapermafrost CR horizon. We found out that the contamination of the soil cover of the industrial site at the Nyurba Mining and Processing Division is of a multielement nature with local highly to very highly contaminated areas. Over a ten-year observation period, areas of stable soil contamination are formed, where the main pollutants are mobile forms of Mn, Zn, Ni. We suggest that against the background of a natural geochemical anomaly associated with trap and kimberlite magmatism, technogenic anomalies are formed in the surface horizons of soils. They are spatially linked to technogenically transformed landscapes. One of the sources of pollutants is the dispersion of the solid phase of dust emissions in the direction of the prevailing winds, which leads to the formation of soils with abnormally high contents of mobile forms of Mn, Zn, Ni.
{"title":"Геохимические свойства и трансформация микроэлементного состава почв при разработке коренных месторождений алмазов в Якутии","authors":"Yana Legostaeva, Anna Gololobova, V. Popov, V. Makarov","doi":"10.31897/pmi.2023.35","DOIUrl":"https://doi.org/10.31897/pmi.2023.35","url":null,"abstract":"Extraction of diamonds from primary deposits in Siberia is associated with the development of kimberlite pipes in challenging environmental conditions, accompanied by a complex impact on the environment. The article presents the results of monitoring the soil cover of the Nakyn kimberlite field in the Yakutia diamond province, which is affected by the facilities of the Nyurba Mining and Processing Division. Development of primary diamond deposits has a large-scale impact on the subsoil, topography, and soil cover: creation of the world's largest quarries, formation of dumps more than 100 m high, arrangement of extensive tailings, formation of solid and liquid industrial wastes of various chemical composition. The research is aimed at studying the spatial and temporal patterns of the technogenic impact on the soil cover, identifying the nature and level of transformation of the microelement composition of soils based on the analysis of the intra-profile and lateral distribution of mobile forms of trace elements. The study targets in 2007-2018 were zonal types of permafrost soils of northern taiga landscapes, cryozems, occupying 84 % of the total study area, which are characterized by biogenic accumulation of mobile forms of Ni, Mn, and Cd in the upper AO, Acr horizons, and Cr, Ni, Co, Mn, Cu in the suprapermafrost CR horizon. We found out that the contamination of the soil cover of the industrial site at the Nyurba Mining and Processing Division is of a multielement nature with local highly to very highly contaminated areas. Over a ten-year observation period, areas of stable soil contamination are formed, where the main pollutants are mobile forms of Mn, Zn, Ni. We suggest that against the background of a natural geochemical anomaly associated with trap and kimberlite magmatism, technogenic anomalies are formed in the surface horizons of soils. They are spatially linked to technogenically transformed landscapes. One of the sources of pollutants is the dispersion of the solid phase of dust emissions in the direction of the prevailing winds, which leads to the formation of soils with abnormally high contents of mobile forms of Mn, Zn, Ni.","PeriodicalId":16398,"journal":{"name":"Journal of Mining Institute","volume":"11 1","pages":""},"PeriodicalIF":2.0,"publicationDate":"2023-04-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75136812","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Growing productivity of mining and processing enterprises entails an increase in the volumes of liquid tailings impoundments and upstream impoundments of ore processing waste. Enterprises face the challenge of minimizing the environmental impact of waste and guaranteeing the sanitary and epidemiological safety of population. The article presents a possibility of recycling one type of such waste (clay-containing concentration tailings of apatite-nepheline and sylvinite ores, coal beneficiation tailings) by using them after preliminary thermochemical treatment as pozzolanic additives to cements and concretes, including concrete mixtures used for soil stabilization, development of territories, reclamation of mine workings, as a component of the insulating layer of landfills for the disposal of municipal solid waste. An analysis of the phase changes of kaolinite, one of the main minerals that make up clay-containing waste, in the temperature range of 200-1,000 °С showed that a change in its mineral form during heat treatment is the main factor in changing its pozzolanic activity. The effect of heat treatment of clay minerals at temperature of 700-800 °C on their pozzolanic activity, estimated by the ability to absorb calcium hydroxide (0.7 g Ca(OH)2 per 1 g of modified kaolinite), is considered. It is shown that the addition of heat-treated samples (20 % by weight) improves the quality of cement increasing its activity by 15 %, in comparison with the use of unmodified clay minerals. It was proved experimentally that partial replacement of Portland cement with thermally modified kaolinite increases the strength of consolidating stowing mixture by up to 15 %. This approach to processing of ores containing layered silicates, which provides for thermochemical modification of run-of-mine ore, intensifies the processes of tailings thickening and filtering.
采矿和加工企业生产力的提高意味着液体尾矿蓄水池和矿石加工废料上游蓄水池的数量增加。企业面临的挑战是尽量减少废物对环境的影响，保证人口的卫生和流行病安全。本文提出了一种回收利用这种废物(含粘土的磷灰石-斜石和钾铁矿的浓缩尾矿，煤炭选矿尾矿)的可能性，通过将它们在初步热化学处理后作为火山灰添加剂使用到水泥和混凝土中，包括用于土壤稳定的混凝土混合物，开发领土，矿山作业的回收，作为垃圾填埋场的保温层的组成部分，用于处理城市固体废物。对构成含泥废物的主要矿物之一高岭石在200 ~ 1000°С温度范围内的物相变化分析表明，热处理过程中其矿物形态的变化是改变其火山灰活性的主要因素。考虑了粘土矿物在700-800°C温度下热处理对其火山灰活性的影响，通过吸收氢氧化钙(每1 g改性高岭石0.7 g Ca(OH)2)的能力来估计。结果表明，与使用未改性的粘土矿物相比，加入热处理样品(重量比为20%)可改善水泥质量，使其活性提高15%。实验证明，用热改性高岭石部分替代波特兰水泥，可使固结充填料的强度提高15%。这种处理含有层状硅酸盐的矿石的方法，为原矿提供了热化学改性，加强了尾矿的浓缩和过滤过程。
{"title":"Использование глиносодержащих отходов в качестве пуццолановых добавок","authors":"A. Gerasimov, Ivan Ustinov, O. Zyryanova","doi":"10.31897/pmi.2023.33","DOIUrl":"https://doi.org/10.31897/pmi.2023.33","url":null,"abstract":"Growing productivity of mining and processing enterprises entails an increase in the volumes of liquid tailings impoundments and upstream impoundments of ore processing waste. Enterprises face the challenge of minimizing the environmental impact of waste and guaranteeing the sanitary and epidemiological safety of population. The article presents a possibility of recycling one type of such waste (clay-containing concentration tailings of apatite-nepheline and sylvinite ores, coal beneficiation tailings) by using them after preliminary thermochemical treatment as pozzolanic additives to cements and concretes, including concrete mixtures used for soil stabilization, development of territories, reclamation of mine workings, as a component of the insulating layer of landfills for the disposal of municipal solid waste. An analysis of the phase changes of kaolinite, one of the main minerals that make up clay-containing waste, in the temperature range of 200-1,000 °С showed that a change in its mineral form during heat treatment is the main factor in changing its pozzolanic activity. The effect of heat treatment of clay minerals at temperature of 700-800 °C on their pozzolanic activity, estimated by the ability to absorb calcium hydroxide (0.7 g Ca(OH)2 per 1 g of modified kaolinite), is considered. It is shown that the addition of heat-treated samples (20 % by weight) improves the quality of cement increasing its activity by 15 %, in comparison with the use of unmodified clay minerals. It was proved experimentally that partial replacement of Portland cement with thermally modified kaolinite increases the strength of consolidating stowing mixture by up to 15 %. This approach to processing of ores containing layered silicates, which provides for thermochemical modification of run-of-mine ore, intensifies the processes of tailings thickening and filtering.","PeriodicalId":16398,"journal":{"name":"Journal of Mining Institute","volume":"75 1","pages":""},"PeriodicalIF":2.0,"publicationDate":"2023-04-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80657284","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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