Design of Capture Materials Utilizing Radiation-Induced Graft Polymerization

Q3 Materials Science Kobunshi Ronbunshu Pub Date : 2018-09-25 DOI:10.1295/KORON.2018-0015
Ryo Ishihara
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引用次数: 1

Abstract

One capturing material can be used for various purposes. For example, the material for capturing analytes, harmful elements, and biomarkers can be used for pretreatment, decontamination, and diagnosis, respectively. The only difference is the target - capture molecules. A large part of the material design strategy can be common. To effectively and quickly develop novel capturing materials, we utilized radiation - induced graft polymerization by selecting the substrate for grafting from the point of view of chemical engineering, applying the desired graft polymerization, and performing subsequent chemical reactions. In this paper, a novel method for determining the mole percentage of an as - formed polymer brush and root is introduced as a new technique for evaluating grafted materials. In addition, according to the above determination technique, an extractant - impregnated porous sheet for rapid analysis and extractant - impregnated non - porous particle for high - resolution separation of rare earth elements were developed. We also developed metal ferrocyanide - impregnated fi bers for radioactive cesium removal and a surface - functionalized power - free micro fl uidic chip for biomarker detection.
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利用辐射诱导接枝聚合设计捕获材料
一种捕获材料可以用于各种目的。例如,用于捕获分析物、有害元素和生物标记物的材料可分别用于预处理、去污和诊断。唯一的区别是目标捕获分子。材料设计策略的很大一部分可以是通用的。为了有效、快速地开发新型捕获材料,我们从化学工程的角度选择接枝底物,应用所需的接枝聚合,并进行后续的化学反应,利用辐射诱导接枝聚合。本文介绍了一种测定聚合物刷根摩尔百分数的新方法,作为评价接枝材料的新技术。此外,根据上述测定技术,研制了用于快速分析的浸渍萃取剂多孔薄片和用于高分辨率分离稀土元素的浸渍萃取剂无孔颗粒。我们还开发了用于放射性铯去除的金属氰化亚铁浸渍纤维和用于生物标志物检测的表面功能化无功率微流体芯片。
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来源期刊
Kobunshi Ronbunshu
Kobunshi Ronbunshu 化学-高分子科学
CiteScore
0.60
自引率
0.00%
发文量
0
审稿时长
6-12 weeks
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