PEMBUATAN DAN KARAKTERISASI ARANG AKTIF DARI BATANG LIMBAH TANAMAN GUMITIR DENGAN AKTIVATOR ZnCl2

E. Sahara, D. E. Permatasaari, I. W. Suarsa
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引用次数: 2

Abstract

The agricultural waste of gumitir plants stem can be used as an ingredient in producing an activated carbon. Some researchers have reported that the additions of phosphoric acid and NaOH as chemical activators have resulted in an activated carbon that met the SNI (Indonesian National Standard) 06-3730-1995 about technical activated carbon. The purpose of this study was to produce and characterize the activated carbon from the stem of gumitir plants carbonized at 300oC for 90 minutes with the use of ZnCl2 as the activator. The activation was carried out by adding ZnCl2 to an amount of carbon in various mole ratios. The characteristics of the activated carbon obtained were compared to the SNI. It was evident that the addition of 0.1 mole of ZnCl2 to 1 gram of the carbon produced an activated carbon that met the SNI standard, namely, water content of 5.00%, as content of 8.33%, volatile content of 950oC of heating  of  7.36%, carbon content of 79,30%, iodine absorption capacity of 788.1271 mg/g, and methylene blue absorption capacity of 260.7917 mg/g. The surface area and surfae acidity of this carbon was of 677,6270 mg2/g and 0.3396 mmol/g, respectively. The functional group analysis of this activated carbon showed the presence of O-H, COOH, C-O aldehyde, alkaline C-C and C-H groups.
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GUMITIR工厂废物棒的活性炭制造和描述与ZnCl2挖掘机
植物茎叶的农业废弃物可作为生产活性炭的原料。有研究报道,添加磷酸和NaOH作为化学活化剂,得到的活性炭符合SNI(印尼国家标准)06-3730-1995关于技术活性炭的标准。本研究的目的是用ZnCl2作为活化剂,以甘油三酯植物茎为原料,在300℃下炭化90分钟,制备活性炭并对其进行表征。通过在不同摩尔比的碳中加入ZnCl2进行活化。所得活性炭的性能与SNI进行了比较。可见,在1克活性炭中加入0.1 mol ZnCl2,制得的活性炭符合SNI标准,即水含量为5.00%,含砷量为8.33%,加热950℃时挥发分含量为7.36%,含碳量为79.30%,碘吸收容量为788.1271 mg/g,亚甲基蓝吸收容量为260.7917 mg/g。该碳的比表面积和表面酸度分别为677、6270 mg2/g和0.3396 mmol/g。官能团分析表明,该活性炭中存在O-H、COOH、C-O醛、碱性C-C和C-H基团。
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