Effect of anodic potential on the characteristics of passive films grown on a brass alloy in a soil environment

Zhihao Liang, K. Jiang, Bai-ao Feng, Lin Li, Ting’an Zhang
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Abstract

The effect of the anode potential on the electrochemical performance and protective ability of the passive film formed on the brass alloy in the soil solution of the Zhouyuan site was investigated by electrochemical measurements, atomic force microscopy, and X‐ray photoelectron spectroscopy. The corrosion resistance of brass alloy in a corrosion soil environment decreases with the increase of applied anodic potential. X‐ray photoelectron spectroscopy results indicate that the passive film is mainly composed of metal oxide. Mott–Schottky results revealed that the passive films behave as p‐type semiconductors at passive potentials and the acceptor density is in the range of 1021 cm−3 and increased with an increase in the film‐forming potential.
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阳极电位对土壤环境下黄铜合金钝化膜特性的影响
采用电化学测量、原子力显微镜和X射线光电子能谱等方法研究了阳极电位对周源土壤溶液中黄铜合金钝化膜的电化学性能和保护能力的影响。黄铜合金在腐蚀土壤环境中的耐蚀性随外加阳极电位的增大而降低。X射线光电子能谱结果表明,钝化膜主要由金属氧化物组成。Mott-Schottky结果表明,钝化膜在钝化电位下表现为p型半导体,受体密度在1021 cm−3范围内,并随着成膜电位的增加而增加。
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