Environmentally friendly polypropylene/poly (trimethylene terephthalate) blend fibers: Resiliency and dyeability

Mohammad Reza Habibolah Zargar, Seyed Rasoul Mousavi, A. Ebrahimzade, S. A. Mousavi Shoushtari, H. Khonakdar
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引用次数: 2

Abstract

An environmentally friendly free-carrier technique was used to prepare poly propylene/poly(trimethylene terephthalate) (PP/PTT) blend fibers. As PTT loading increased, its average diameter enhanced, and its distribution narrowed. In addition, the results of mechanical properties demonstrated that incorporating PTT into the PP matrix led to a decrease in tenacity and elongation-at-break. The more the PTT content, the less the tenacity and the elongation-at-break. Moreover, the crystallinity of PP enhanced by about 12% when 20 wt.% PTT was incorporated while melting and crystallization temperatures did not change remarkably. The molten blends indicated almost a Newtonian behavior. On the other hand, the storage modulus enhanced almost linearly in the frequency range of 1–1000 1/sec for all samples. Also, approximately 60% improvement in dyeability and 10% progress in resiliency behavior were observed. The dye uptake ability of samples was improved with the addition of PTT. In addition, the washing and light fastness of the blends were admissible for textile fibers. Generally, blends with PTT content less than 20 wt.% exhibited better physical and mechanical properties, especially resiliency behavior. Therefore, PP/PTT blend fibers are promising candidates for use in textiles in the coming years.
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环保型聚丙烯/聚对苯二甲酸三甲基酯混纺纤维:弹性和可染性
采用环境友好型自由载体技术制备聚丙烯/聚对苯二甲酸三甲酯(PP/PTT)共混纤维。随着PTT载荷的增加,其平均直径增大,分布变窄。此外,力学性能结果表明,在PP基体中加入PTT会导致韧性和断裂伸长率下降。PTT含量越高,韧性和断裂伸长率越低。当PTT添加量为20wt .%时,PP的结晶度提高了约12%,而熔融和结晶温度没有显著变化。熔融混合物几乎表现出牛顿力学的行为。另一方面,所有样品的存储模量在1 - 1000 1/秒的频率范围内几乎呈线性增加。此外,染料可染性提高约60%,回弹性性能提高约10%。PTT的加入提高了样品的染料吸收能力。此外,共混物的洗涤性和耐光牢度对纺织纤维来说是可以接受的。一般来说,PTT含量小于20wt .%的共混物具有较好的物理力学性能,特别是回弹性能。因此,PP/PTT共混纤维在未来几年将有很好的应用前景。
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