Separation of alcohol/water mixtures by pervaporation through zeolite A membranes

Jalal J. Jafar, Peter M. Budd
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引用次数: 100

Abstract

Zeolite NaA membranes were prepared from homogeneous solution on macroporous zirconia composite supports in sheet and tube form. Zeolite KA membranes were obtained by ion exchange from the sodium form. The membranes were tested for the removal of water from isopropanol/water mixtures by pervaporation. Feed and permeate compositions and flux were measured for pervaporation at 25 and 70°C. Both the Na and K forms of zeolite A membranes were highly selective, separation factors in excess of 104 being achieved at low concentrations of water in the feed. Membrane performance was not affected by heat treatments to 150°C.

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沸石A膜渗透蒸发分离酒精/水混合物
采用均相溶液在大孔氧化锆复合材料载体上制备了片状和管状分子筛NaA膜。采用离子交换法制备KA型沸石膜。通过渗透汽化测试了膜对异丙醇/水混合物的去除率。在25°C和70°C下测量进料和渗透成分和通量。沸石A膜的Na和K形式都具有高度选择性,在饲料中低浓度水的情况下,分离系数超过104。膜的性能不受热处理至150°C的影响。
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Author index Subject index Contents Investigation of organosilanes as structure-directing agents in zeolite synthesis The influence of gel properties on the kinetics of crystallization and particulate properties of MFI-type zeolities. I. The influence of time and temperature of gel ageing on the particulate properties of silicalite-1 microcrystals
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