Crystal Growth and Characterization of a New NLO Material: p-Toluidine p-Toluenesulfonate

Abstract

Single crystals of p-Toluidine p-Toluenesulfonate (PTPT), an organic nonlinear optical (NLO) material, have been grown by slow evaporation method at room temperature using ethanol as solvent. The crystal system was confirmed from the single crystal X-ray diffraction analysis. The functional groups were identified using FTIR spectroscopy. UV-Vis-NIR spectrum showed that the UV cut-off wavelength of PTPT occurs at 295 nm and it has insignificant absorption in the wavelength region of 532–800 nm. The SHG efficiency of PTPT was measured by employing Kurtz and Perry powder technique using a Q-switched mode locked Nd: YAG laser emitting 1064 nm for the first time and it was found to be 52% of standard KDP. Thermal and mechanical properties of PTPT were examined by TG/DTA and Vickers microhardness test, respectively.