Thermodynamics of the Vitrified Bottom Ash Slag from Municipal Solid Waste Incinerators-Phase Relations of CaO-SiO2-Na2O Oxide System

Zhan Zhang, Guangqiang Li, Y. Yang, Yan-ping Xiao
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引用次数: 4

Abstract

Vitrification is considered to be an attractive technology for municipal solid waste incineration. The main components of the vitrified bottom ash slag are SiO2, CaO, Al2O3, Fe2O3, Na2O and MgO, accounting for more than 90% of the total mass. The phase relations and thermodynamic properties of the CaO-Al2O3-SiO2-FeOx-MgO-Na2O oxide system is highly required, and is of great significance for optimization of vitrification processing and sustainable resource utilization of melting slag. Thermodynamic properties of the vitrified bottom ash slag were investigated in the present work. A study on the phase equilibria of CaO-SiO2-Na2O system was carried out with modelling method.
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城市生活垃圾焚烧炉玻璃化底灰渣的热力学——CaO-SiO2-Na2O氧化物体系的相关系
玻璃化技术被认为是一种有吸引力的城市生活垃圾焚烧技术。玻璃化底灰渣的主要成分为SiO2、CaO、Al2O3、Fe2O3、Na2O和MgO,占总质量的90%以上。研究CaO-Al2O3-SiO2-FeOx-MgO-Na2O氧化物体系的物相关系和热力学性质,对熔融渣玻璃化工艺优化和资源可持续利用具有重要意义。对玻璃化底灰渣的热力学性质进行了研究。采用模拟方法对CaO-SiO2-Na2O体系的相平衡进行了研究。
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