Bondlength alternation of nanoparticles Fe2O3 coated with organic surfactants probed by EXAFS

T Liu , L Guo , Y Tao , T.D Hu , Y.N Xie , J Zhang
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引用次数: 25

Abstract

The nanoparticles γ-Fe2O3 coated with surfactants, DBS, ST and CTAB, repsectively, were synthesized by microemulsion method. The coated ferric oxides, which show enhanced nonlinear optical properties compared with their bulk counterpart, were probed by EXAFS in solution forms. The x-ray absorption spectra for Fe K edge were measured at room temperature by help of synchrotron radiation light source. Extended x-ray absorption fine structure analysis shows that the coating layers of organic molecules interact with surface atoms of nanoparticles, the Fe-O bond length was extended.

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用EXAFS探测有机表面活性剂包覆纳米Fe2O3的键长变化
采用微乳液法制备了表面活性剂DBS、ST和CTAB包覆的纳米γ-Fe2O3。用EXAFS对包覆后的三氧化铁溶液进行了探测,结果表明包覆后的三氧化铁具有增强的非线性光学性质。在同步辐射光源的帮助下,测量了Fe - K边在室温下的x射线吸收光谱。扩展x射线吸收精细结构分析表明,有机分子涂层与纳米粒子表面原子相互作用,Fe-O键长度被延长。
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