Nickel (Ii) Ion Desorption Kinetic Modeling From Unmodified and Chemically Modified Oil Palm (Elaeis Guineensis) Fruit Fibre Adsorbents

A. Abia, E. Asuquo, J. C. Igwe
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引用次数: 1

Abstract

The desorption of Ni2+ from three oil palm fruit fibre adsorbents (UOPF, 0.5MOPF and 1.0MOPF) using five desorbing solutions showed a desorption efficiency following the trend, 0.1M HCl > 0.1MH2SO4 > 0.1MHNO3 > 0.1MNaOH >hot deionized H2O. The Elovich desorption constant, β values for the 0.1MHCl desorbent were: 6.45 X10-1, 5.57 x 10-1 and 4.34 x 10-1g. mg-.min-1 for UOPF,0.5MOPF and 1.0MOPF adsorbents respectively. The surface residence time  values for the 0.1MHCl desorbent were; 32.3, 28.6 and 26.8 seconds for UOPF, 0.5MOPF and 1.0MOPF adsorbents respectively. Kinetic modeling analysis of the Elovich and pseudo-first order desorption equations, indicates that the latter model described the desorption of Ni2+ better. Keywords: Nickel, desorption, modeling, kinetics, Elovich, oil palm.
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未改性和化学改性油棕果纤维吸附剂镍离子解吸动力学模型研究
5种解吸溶液对三种油棕果纤维吸附剂(UOPF、0.5MOPF和1.0MOPF)中Ni2+的解吸效果为:0.1M HCl > 0.1MH2SO4 > 0.1MHNO3 > 0.1MNaOH >热去离子水。0.1MHCl脱附剂的Elovich脱附常数β值分别为:6.45 × 10-1、5.57 × 10-1和4.34 × 10-1g。mg -。UOPF、0.5MOPF和1.0MOPF吸附剂分别为min-1。0.1MHCl脱附剂的表面停留时间值为;UOPF、0.5MOPF和1.0MOPF吸附剂分别为32.3、28.6和26.8秒。对Elovich和拟一阶解吸方程的动力学建模分析表明,后一阶解吸方程能更好地描述Ni2+的解吸过程。关键词:镍,解吸,建模,动力学,Elovich,油棕。
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