OBTAINING AND STUDY OF OLIGOMERIC SURFACTANT BASED ON OCTADECYLAMINE AND OXYPROPYLENE

S. Zargarova
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Abstract

Oligomeric surfactant based on octadecylamine and propylene oxide was synthesized. The degrees of oligomerization of octadecylamine was calculated as 6.2 Structure and composition of the surfactant was confirmed by using IR and UV-spectroscopy. Surface tension values with respect to concentration were examined and respective curve was plotted. Also, main surf activity parameters like CMC, CMC, πCMC, C20, pC20, Γmax, Amin were calculated. Critical micelle concentrations (CMC) and surface tensions at CMC were calculated as 1.58*10-4 mol/l and 31.92 mN/m respectively. Petrocollecting property and petrocollecting coefficients of the surfactant were studied for distilled, tap and sea water.
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十八胺-氧丙烯低聚表面活性剂的制备与研究
以十八胺和环氧丙烷为原料合成了低聚表面活性剂。通过红外光谱和紫外光谱分析,确定了表面活性剂的结构和组成。检测了与浓度相关的表面张力值,并绘制了相应的曲线。并计算了CMC、CMC、πCMC、C20、pC20、Γmax、Amin等主要冲浪活性参数。临界胶束浓度(CMC)为1.58*10-4 mol/l,表面张力为31.92 mN/m。研究了表面活性剂对蒸馏水、自来水和海水的集油性能和集油系数。
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