Physicochemical and Polycyclic Aromatic Hydrocarbons (PAHs) Analysis in Soil and Sediment from Vicinity of Ikot Akpaden, Akwa Ibom State, Nigeria

U. U. Ubong, E. Ikpe, I. Ekwere, Emaime J. Uwanta
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Abstract

The study was undertaken to determine the levels of 16 priority PAHs in soil and sediments from some vicinities of Ikot Akpaden, Mkpat Enin. The soils were prepared using standard procedure in the laboratory and analyzed for 16 US EPA priority PAHs using Gas Chromatography-Mass Spectrophotometer (GC-MS). The soil samples were obtained from two sampling sites at Ikot Akpaden (Site A and C). Site C showed minimal PAHs concentration while site A recorded PAHs levels ranging from 0.01 to 4.25 mg/kg. According to European commission, the PAHs concentrations in soil samples of this study are moderate, but deleterious over time. The soils were negatively affected more with low molecular weight PAHs than High Molecular Weight PAHs.This study revealed that the sampling sites had low carcinogenic burden, hence would exhibit moderate adverse health effects to plants and animals. It was concluded that automobile repair activities in site A contributed to the soil contamination with PAHs; hence it should be properly sited.
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尼日利亚阿夸伊博姆州Ikot Akpaden附近土壤和沉积物的理化和多环芳烃(PAHs)分析
进行这项研究是为了确定伊科特阿克帕登和姆帕特埃宁一些地区土壤和沉积物中16种重点多环芳烃的含量。采用实验室标准工艺制备土壤,采用气相色谱-质谱联用仪(GC-MS)对16种美国环保局优选的多环芳烃进行分析。土壤样品取自Ikot Akpaden的两个采样点(A点和C点),C点的多环芳烃含量最低,而A点的多环芳烃含量为0.01 ~ 4.25 mg/kg。根据欧盟委员会的报告,本研究土壤样品中的多环芳烃浓度是中等的,但随着时间的推移是有害的。低分子量多环芳烃对土壤的负面影响大于高分子量多环芳烃。本研究表明,采样点的致癌负担较低,因此对植物和动物的不良健康影响较小。结论:A点的汽车修理活动是造成土壤多环芳烃污染的主要原因;因此,它应该是适当的位置。
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