ADSORPSI SENYAWA MONOMER PIROL OLEH KARBON AKTIF MAGNETIK (ADSORPTION OF PYROL MONOMER COMPOUNDS BY MAGNETIC ACTIVE CARBON)

Berta Juniarty Antomy, M. A. Wibowo, N. Wahyuni
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Abstract

Magnetic activated carbon (KAM) is used as an absorbent or adsorbent based on coconut shell which has been activated with sodium bicarbonate. The activated carbon is added to the iron composite which produces KAM. The iron composite content in the adsorbent has the ability to absorb and facilitate the separation process on the adsorbate. The purpose of this study was to determine the ability of the adsorbent to absorb the adsorbate, namely the pyrrole monomer compound. The adsorbent was characterized using the Fourier Transform Infra-Red (FTIR) instrument to determine the functional groups present. The adsorption capacity of iodine and methylene blue, adsorption isotherm, and adsorption kinetics were analysis. The adsorption isotherm was determined by varying the pyrrole concentration from the range of 30; 40; 50; 60 and 70 ppm. Determination of time variation was also carried out on adsorption kinetics with a range of 1; 1.5; 2; 2.5 and 3 hours. The FTIR spectrum produces Fe-O functional groups with an absorption peak of 556 cm-1, indicating the presence of a magnetic composite that has been attached to carbon. The adsorption capacity of iodine and methylene blue on magnetic activated carbon are 527 mg/g and 699 mg/g, respectively. The adsorption kinetics on KAM with the first-order model resulted in a value of R2=0.7736
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磁性吸附多酚类单体化合物(磁性活性炭吸附多酚类单体化合物)
磁性活性炭(KAM)是一种以碳酸氢钠活化的椰子壳为基材的吸附剂。将活性炭加入到铁复合材料中,产生KAM。吸附剂中的铁复合含量具有吸附能力,有利于吸附物的分离过程。本研究的目的是测定吸附剂对吸附物即吡咯单体化合物的吸附能力。利用傅里叶变换红外光谱(FTIR)对吸附剂进行表征,确定其官能团。分析了其对碘和亚甲基蓝的吸附量、吸附等温线和吸附动力学。通过改变吡咯浓度在30范围内的变化来确定吸附等温线;40;50;60和70ppm。吸附动力学的时间变化范围为1;1.5;2;两个半小时到三个小时。FTIR光谱产生Fe-O官能团,其吸收峰为556 cm-1,表明存在附着在碳上的磁性复合材料。磁性活性炭对碘和亚甲基蓝的吸附量分别为527 mg/g和699 mg/g。在一阶模型下,其吸附动力学系数R2=0.7736
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