Pure and Al-Bi Co-doped SnO2 nanoparticles as bacterial growth inhibitors

Anuja E., P. A., R. Brindha, V. I
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Abstract

Abstract The present work is aimed to prepare un-doped and aluminium-bismuth co-doped tin-oxide nanoparticles with 2 weight percentages (each co-dopant 2 wt %) and 4 weight percentages (each 4 wt %) by employing a co-precipitation method. Tetragonal rutile crystal structure of the synthesized materials was confirmed by powder X-ray diffraction, bandgap energy by UV-Vis diffuse reflectance spectral analysis, chemical bonding and the position of O-Sn-O by Fourier transform infrared spectrum and morphology through scanning electron microscopy. The photoluminescence spectrum of synthesized nanoparticles shows emission peaks at 490, 520 and 536 nm. Antibacterial activity of Al-Bi co-doped (4 wt %) SnO2 nanoparticles shows a higher zone of inhibition in the range of 20–36 mm against Staphyllococcus aureus, 25–34 against Bacillus cereus and 30–41 against Escherichia Coli than pure SnO2 nanoparticles. The developed oxygen vacancies due to the addition of dopants increase the generation of reactive oxygen species which increases the inhibition capability of tin-oxide nanoparticles against various bacterial species.
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纯和Al-Bi共掺杂SnO2纳米颗粒作为细菌生长抑制剂
摘要采用共沉淀法制备了2重量百分比(每个共掺杂2 wt %)和4重量百分比(每个共掺杂4 wt %)的未掺杂和铝铋共掺杂氧化锡纳米颗粒。通过粉末x射线衍射,紫外-可见漫反射光谱分析,带隙能量分析,傅里叶变换红外光谱,O-Sn-O的化学键和位置,扫描电镜形貌,证实了合成材料的四方金红石晶体结构。合成的纳米颗粒在490、520和536 nm处有发光峰。与纯SnO2纳米颗粒相比,Al-Bi共掺杂(4 wt %) SnO2纳米颗粒对金黄色葡萄球菌的抑菌活性在20-36 mm范围内更高,对蜡样芽孢杆菌的抑菌活性在25-34 mm范围内更高,对大肠杆菌的抑菌活性在30-41 mm范围内更高。由于掺杂剂的加入而形成的氧空位增加了活性氧的生成,从而提高了氧化锡纳米颗粒对各种细菌的抑制能力。
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