Anode behavior and oxidation of Zn22Al alloy doped with scandium

M. M. Mirmukhamedov, U. R. Jobirov, I. Ganiev, Z. Obidov
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Abstract

The article contains the results of potentiodynamic and thermogravimetric research of anode behavior and oxidation of Zn22Al alloy, doped with scandium, in various media. The anode, kinetic and energy characteristics of alloys in isothermal conditions have been established. Doping of the Zn22Al alloy with scandium in an amount of 0.1 to 1.0 wt. % contributes to the increase of its anodic resistance to oxidation. The rate of oxidation and corrosion of alloys doped (0.01–0.1%) with scandium is 1.5–3 times lower than that of the Zn22Al alloy. Alloy oxidation products consist of a mixture of protective films ZnO, Sc2O3, ZnAl2O4 and Al2O3·Sc2O3. 
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掺钪Zn22Al合金的阳极行为与氧化
本文介绍了掺杂钪的Zn22Al合金在不同介质中的阳极行为和氧化的动电位和热重研究结果。建立了合金在等温条件下的阳极、动力学和能量特性。在Zn22Al合金中掺入0.1 ~ 1.0 wt. %的钪有助于提高Zn22Al合金的阳极抗氧化性。掺钪(0.01 ~ 0.1%)合金的氧化腐蚀速率比Zn22Al合金低1.5 ~ 3倍。合金氧化产物由保护膜ZnO、Sc2O3、ZnAl2O4和Al2O3·Sc2O3的混合物组成。
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