Multiwalled carbon nanotubes reinforced flexible blend nanocomposites membranes for pervaporation separation of aromatic-aliphatic mixtures

S. Thomas, Shaji P. Thomas, Sujit A. Kadam, Thomasukutty Jose, Jiji Abraham, S. C. George, Sabu Thomas
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引用次数: 1

Abstract

Multiwalled carbon nanotubes (MWCNT) reinforced NR-NBR blend nanocomposite membranes were prepared and potentially employed for the pervaporation separation of aliphatic – aromatic mixtures. For a 50 wt% benzene feed, the blend nanocomposite membranes had a total flux of 1.265 kgm−2h−1 and separation factor of 1.59 at room temperature. The blend membranes exhibited aromatic selectivity for the separation of aromatic – aliphatic mixtures. 2 phr MWCNT/blend nanocomposite membranes exhibited similar trend for the separation of 10 wt% feed toluene mixture. Trasmission electron microscopy (TEM) images of the blend nanocomposites revealed the well dispersion and distribution of MWCNT in the polymer matrix. The well dispersed MWCNT/blend membranes selectively separate aromatic components from aliphatic – aromatic mixtures.
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多壁碳纳米管增强柔性共混纳米复合材料膜用于芳香-脂肪族混合物的渗透汽化分离
制备了多壁碳纳米管(MWCNT)增强NR-NBR共混纳米复合膜,该膜有望用于脂肪族-芳香族混合物的渗透蒸发分离。在苯质量分数为50%的情况下,室温下共混纳米复合膜的总通量为1.265 kgm−2h−1,分离系数为1.59。共混膜对芳香族-脂肪族混合物的分离表现出芳香选择性。2 phr MWCNT/共混纳米复合膜对10 wt%的饲料甲苯混合物表现出类似的分离趋势。共混纳米复合材料的透射电镜(TEM)图像显示MWCNT在聚合物基体中的分散和分布良好。分散良好的MWCNT/共混膜可选择性地从脂肪族-芳香族混合物中分离芳香族成分。
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