Enhanced electrochemical pseudocapacitance performance of poly tyramine composite on the surface of polyethylene glycol modified electrode

IF 2.1 4区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Plastics, Rubber and Composites Pub Date : 2023-06-11 DOI:10.1080/14658011.2023.2219085
A. Ehsani, M. Moftakhar
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Abstract

ABSTRACT In the present study, we introduce the first study for investigating the effect of polyethylene glycol (PEG) on the electrochemical performance of the PTy electroactive film. In this work, we applied PEG to improve electrochemical performance of PTy electroactive film. The electrochemical properties of the prepared electrodes were investigated by means of various electrochemical methods including electrochemical impedance spectroscopy (EIS), cyclic voltammetry (CV) and consecutive charge/discharge. The developed electrode in this study exhibits a specific capacity of 4200 mF.cm−2 at 5 mA.cm−2 current density while retaining 90% of the initial capacitance after 3000 cycles. Our results provide an improved conductive polymer composite film with high active surface area, ease of synthesis and high cycling stability for supercapacitors (SCs) in aqueous electrolytes. GRAPHICAL ABSTRACT
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聚酪胺复合材料在聚乙二醇修饰电极表面的电化学赝电容性能增强
摘要:本文首次研究了聚乙二醇(PEG)对PTy电活性膜电化学性能的影响。在这项工作中,我们应用聚乙二醇来改善PTy电活性膜的电化学性能。采用电化学阻抗谱(EIS)、循环伏安法(CV)和连续充放电等电化学方法对制备的电极的电化学性能进行了研究。本研究开发的电极具有4200mf的比容量。cm−2在5ma。Cm−2电流密度,同时在3000次循环后保持90%的初始电容。我们的研究结果为超级电容器(SCs)提供了一种具有高活性表面积、易于合成和高循环稳定性的导电聚合物复合膜。图形抽象
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来源期刊
Plastics, Rubber and Composites
Plastics, Rubber and Composites 工程技术-材料科学:复合
CiteScore
4.10
自引率
0.00%
发文量
24
审稿时长
4 months
期刊介绍: Plastics, Rubber and Composites: Macromolecular Engineering provides an international forum for the publication of original, peer-reviewed research on the macromolecular engineering of polymeric and related materials and polymer matrix composites. Modern polymer processing is increasingly focused on macromolecular engineering: the manipulation of structure at the molecular scale to control properties and fitness for purpose of the final component. Intimately linked to this are the objectives of predicting properties in the context of an optimised design and of establishing robust processing routes and process control systems allowing the desired properties to be achieved reliably.
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