Dissipation rates of some selected pesticides from the soil of tea agroecosystem in Assam, India

Yumnam Devashree, B. Dutta, S. Paul, Sudip Choudhury
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Abstract

An experiment was carried out in Rosekandy Tea Estate, Barak Valley, Assam to investigate the persistence of some selected pesticides (i.e Endosulfan, Fipronil, Paraquat and 2,4-D) on the soil. These pesticides were applied in the soil as per the application rate, where one year old tea plants were growing and the residue were analysed for a period of 50 days. Their degradation kinetics in soil was also studied and described. Soil samples were collected with the help of soil corer. The samples were brought to the laboratory, air dried in room temperature and extracted for analysis with high performance liquid chromatography (HPLC). Among the pesticides 2,4-D was highly persistent with half life of 57.75 days followed by Endosulfan which lost 42.64% of its initial concentration by the last sampling period (i.e 50 days) after the spraying. Fipronil and paraquat lost 65% and 70.32% of initial residue in soil making them the least persistent amongst these pesticides in the studied soil. Considering the impact of pesticide residues on human health, the less persistent pesticides may be used in tea plantations to minimize the potential negative impact of pesticides in the environment. The cost benefit ratios of the use of the pesticides should be also worked out.
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印度阿萨姆邦茶叶农业生态系统土壤中某些农药的耗散率
在阿萨姆邦巴拉克山谷的罗斯坎迪茶园进行了一项试验,以调查一些选定的农药(即硫丹、氟虫腈、百草枯和2,4- d)在土壤上的持久性。这些农药按施药率施用于土壤中,在生长了一年的茶树的土壤中,对残留进行了为期50天的分析。研究并描述了它们在土壤中的降解动力学。利用土壤覆盖物采集土壤样品。样品被带到实验室,在室温下风干,提取用于高效液相色谱(HPLC)分析。其中,4-D的持久性较强,半衰期为57.75 d,其次是硫丹,在喷洒后最后一个采样期(即50 d),硫丹的半衰期下降了42.64%。氟虫腈和百草枯在土壤中损失了65%和70.32%的初始残留,使它们在所研究的土壤中持久性最低。考虑到农药残留对人体健康的影响,可以在茶园中使用持久性较低的农药,以尽量减少农药对环境的潜在负面影响。还应计算出使用农药的成本效益比。
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