アパタイト型Ndx(SiO4)6O1.5x−12単結晶のEPMAによって決定された組成と伝導率の関係

享 中山, 幹雄 樋口, 和義 上松
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引用次数: 2

Abstract

Four kinds of single crystals of hexagonal apatite type Ndx(SiO4)6O1.5x−12 (x = 8–9.33), which is an oxide ionic conductor, were prepared by the FZ method and samples for electrical measurements (the conductivity components parallel and perpendicular to the c-axis of single crystal) were prepared. The conductivities of the component parallel to the c-axis were higher about one order of magnitude, compared with those of the component perpendicular. The values of (Nd/Si) × 6 of four kinds of samples were 8.63, 8.67, 8.91 and 9.33 determined by electron probe micro-analysis. The conductivity was slightly increased with decreasing the value of (Nd/Si) × 6.
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磷灰石型Ndx(SiO4) 6o1.5 x - 12单结晶EPMA确定的组分和电导率的关系
采用FZ法制备了四种氧化离子导体六方磷灰石型Ndx(SiO4)6O1.5x−12 (x = 8-9.33)单晶,并制备了电学测量样品(平行于单晶c轴和垂直于单晶c轴的电导率分量)。与垂直于c轴的电导率相比,平行于c轴的电导率约高一个数量级。四种样品的(Nd/Si) × 6分别为8.63、8.67、8.91和9.33。随着(Nd/Si) × 6值的减小,电导率略有提高。
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