Dielectric Study of Pure Propan-1-OL and Propan-2-OL Using Debye Relaxation Method

M. Onimisi, J. Ikyumbur
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Abstract

The Debye relaxation equation and its derivatives were used to analyze the experimental permittivity data of high purityPropan-1-ol and Propan-2-ol over the frequency up to 10GHz and temperature range of 10oC to 50oC. The plots of dielectric constant ε and loss factor ε against the frequency were found useful in determining how well experimental data fits the Debye equation and these methods were also found capable of reproducing good results of fitted data using doubleDebye. The dielectric constant of Propan-1-ol was found to decrease as the temperature increases beyond 10oC whereas that of Propan-2-ol increased at the temperature 20oC. It then decreased as the temperature increased beyond 20oC. The loss factor on the other hand was found decreasing as the temperature increases for both Propan-1-ol and Propan-2-ol. This work also reveals that Propan-2-ol at 20oC followed Debye relaxation equation only at frequency range 5GHz.
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用Debye松弛法研究纯丙烷-1-醇和丙烷-2-醇的介电性质
利用Debye弛豫方程及其导数分析了高纯度丙烷-1-醇和丙烷-2-醇在10GHz频率和10oC ~ 50oC温度范围内的实验介电常数数据。介电常数ε和损耗因子ε随频率的变化曲线可用于确定实验数据与Debye方程的拟合程度,并且这些方法也能再现双Debye拟合数据的良好结果。在温度超过10℃时,介电常数随温度升高而降低,而在温度超过20℃时介电常数升高。当温度超过20℃时,它会下降。而丙烷-1-醇和丙烷-2-醇的损失因子随着温度的升高而减小。本研究还揭示了20℃时丙二醇仅在5GHz频率范围内符合Debye弛豫方程。
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