Oxidative Carbonylation of 2-Propyn-1-ol and 2-Methyl-3-butyn-2-ol in an Oscillatory Mode

S. N. Gorodsky
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引用次数: 4

Abstract

The oscillatory modes of oxidative carbonylation reaction of two new substrates—2-methyl-3-butyn-2-ol and 2-propyn-1-ol in homogeneous system PdI2-KI-CO-O2-CH3OH are found. Borders of oscillatory areas are drawn, the basic products of reaction are identified, and probable processes routes are offered.
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2-丙基-1-醇和2-甲基-3-丁-2-醇在振荡模式下的氧化羰基化反应
发现了PdI2-KI-CO-O2-CH3OH均相体系中2-甲基-3-丁-2-醇和2-丙-1-醇两种新底物氧化羰基化反应的振荡模式。绘制了振荡区域的边界,确定了反应的基本产物,并给出了可能的过程路线。
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