Characterization of Zinc Oxide Nanoparticle from Waste Cooking Oil for Surface Coating

Nurul Hidayah Harun, R. Rohani, Nur Syafiqah Farhanah Dzulkharnien
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Abstract

The use of nanoparticles (nps) for surface coating has increased the researcher's interest in it due to its inherent properties, especially from metal oxide such as zinc oxide (ZnO). It is ideal for combining the coating solution because of its low cost and smaller pigments. Bio-organic materials are used for synthesis of ZnO to produce green or eco-friendly products as well as to replace polymers derived from traditional petroleum. This study aimed to incorporate ZnO into the surface coating with its potential properties to be used as an effective surface coating material. This study was focused on the synthesis of ZnO from waste cooking oil (WCO) via encapsulation of ZnO with APO obtained from WCO, followed by characterization and testing for its suitability in surface coating application. The characteristics of ZnO nps were studied by using the infrared spectroscopy of Fourier transformation (FTIR), x-ray diffraction (XRD), UV spectrum (UV-Vis) and scanning electron microscope (SEM). FTIR analysis is unable to confirm the existence of ZnO nps because it does not show maximum absorption at wavelength of 421 cm-1. X-ray (XRD) shows the particles are in high amorphous conditions. ZnO nps exhibits UV-VIS absorption at a wavelength 330 nm that provides anti-UV property. Analysis from SEM showed Zn element is absent in the dispersion of ZnO-APO paint morphology. In addition, the effectiveness of the antibacterial properties of the ZnO nps for surface coating does not show any inhibition of the bacteria, methicillin-resistant Staphylococcus aureus (MRSA) and Klebsiella pneumoniae (K. pneumoniae). Therefore, better methods of production need to be examined to help in the encapsulation of ZnO nps. The suitability of the organic or inorganic surface coating material is also needed to be explored in by further characterizing the materials based on its composition, strength and effectiveness.
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废食用油纳米氧化锌表面涂层的表征
纳米粒子(nps)用于表面涂层,由于其固有的性质,特别是从金属氧化物如氧化锌(ZnO)的使用,增加了研究人员的兴趣。它是理想的结合涂层溶液,因为它的低成本和更小的颜料。生物有机材料用于合成氧化锌,生产绿色或环保产品,并取代传统石油衍生的聚合物。本研究旨在将ZnO加入到表面涂层中,利用其潜在的性能作为一种有效的表面涂层材料。以废食用油(WCO)为原料,用从WCO中获得的APO包封ZnO,制备了氧化锌,并对其进行了表征和表面涂层性能测试。采用红外傅立叶变换(FTIR)、x射线衍射(XRD)、紫外光谱(UV- vis)和扫描电子显微镜(SEM)研究了ZnO nps的特征。FTIR分析无法证实ZnO nps的存在,因为它在421 cm-1波长处没有显示出最大吸收。x射线(XRD)分析表明,颗粒处于高度非晶状态。ZnO nps在波长330 nm处具有紫外-可见吸收,具有抗紫外特性。SEM分析表明,ZnO-APO涂料的分散形貌中不存在Zn元素。此外,ZnO nps表面涂层的抗菌性能并未显示出对耐甲氧西林金黄色葡萄球菌(MRSA)和肺炎克雷伯菌(K. pneumoniae)细菌的抑制作用。因此,需要研究更好的生产方法来帮助ZnO nps的封装。有机或无机表面涂层材料的适用性也需要通过对材料的组成、强度和有效性进行进一步的表征来探索。
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