Study of Test Method for Adhesion of Hydrophobic Insulating Coating on Insulator Metal Fitting Surface

Shihong Hu, Jie-Wang, P. Tang, Jun Zhu, Shisong Yang, Xiaobin Cao
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引用次数: 1

Abstract

At present, the phenomenon of corrosion of insulator on direct current (DC) transmission line is prominent, it is possible to prevent insulator from being corroded by adding a hydrophobic insulation coating on the surface of the insulator. Silicone rubber (PRTV) coatings are commonly used as hydrophobic insulation coatings, but the adhesion of PRTV coatings on the surface of insulator metal fitting is not good. The test methods for coating adhesion currently given in China are relatively simple and lack quantitative indicators. In this paper, the adhesion test methods of PRTV and polyvinylidene fluoride (PVDF) on the surface of A3 steel and hot-dip galvanized metal are studied, and to research the effect of dopamine as an intermediate adhesion promoter. First, two kinds of metal coating tests were prepared, and a pull-off test device was set up. According to the pull-off test, it was found that when different coating samples were bonded to the test metal fixture, the bonding effect was significantly different. When PRTV coating samples are bonded to test columns, need to use fast-drying cyanoacrylate adhesive, epoxy adhesive cannot effectively bond PRTV samples and fixtures. When PVDF coating samples and test columns are bonded, the adhesion of epoxy resin adhesive is much stronger than fast-drying cyanoacrylate adhesive. The experimental test results show that after dopamine is used as the intermediate adhesion layer, the adhesion of the PVDF coating on the galvanized substrate is stronger than the ungalvanized sample; the ungalvanized PVDF sample has about 2 times the adhesion improvement than the galvanized PRTV sample; Under the situation that the adhesion of ungalvanized PVDF samples is enhanced, the adhesion of galvanized PVDF samples is about 2 times higher than ungalvanized PVDF samples. It can be found that PVDF coatings have significantly improved the adhesion index compared to PRTV coatings. This article can provide a reference for the requirements of insulator coating adhesion test.
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绝缘子金属接头表面疏水绝缘涂层附着力试验方法的研究
目前,直流输电线路上绝缘子腐蚀的现象比较突出,可以通过在绝缘子表面加一层疏水绝缘涂层来防止绝缘子被腐蚀。硅橡胶(PRTV)涂料是常用的疏水绝缘涂料,但PRTV涂料在绝缘子金属接头表面的附着力不好。目前国内给出的涂层附着力测试方法比较简单,缺乏定量指标。本文研究了PRTV和聚偏氟乙烯(PVDF)在A3钢和热镀锌金属表面的附着力测试方法,并研究了多巴胺作为中间附着力促进剂的作用。首先,制备了两种金属涂层试验,并建立了拉脱试验装置。通过拉脱试验发现,当不同的涂层样品与测试金属夹具结合时,结合效果有显著差异。当PRTV涂层样品粘接到测试柱上时,需要使用快干氰基丙烯酸酯胶粘剂,环氧胶粘剂不能有效粘接PRTV样品和固定装置。当PVDF涂层样品与测试柱粘合时,环氧树脂胶粘剂的附着力比快干氰基丙烯酸酯胶粘剂强得多。实验测试结果表明,以多巴胺作为中间粘附层后,PVDF涂层在镀锌基体上的粘附力比未镀锌样品强;未镀锌PVDF样品的附着力提高约为镀锌PRTV样品的2倍;在未镀锌PVDF样品附着力增强的情况下,镀锌PVDF样品的附着力比未镀锌PVDF样品高2倍左右。可以发现,与PRTV涂层相比,PVDF涂层的附着力指数明显提高。本文可为绝缘子涂层附着力试验的要求提供参考。
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