Study on polyurethane-based porous materials and their adsorption properties

Jiajia Li, Jiahui Zhu, Jialin Gu, Zhenhao Zhou, Q. Sun, Guangcan Guo, Yibin Zhou, Shujun Chen, Xinggang Shan, Gangqiang Wang
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Abstract

The flexible superhydrophobic thermoplastic polyurethane(TPU) porous   material was prepared by heat-induced phase separation method with two cooling steps. The influence of the preparation process on the microstructure of the material was discussed in depth. The microstructure, hydrophobicity and specific surface area of porous TPU materials were analyzed in detail. The surface wettability, separation selectivity, saturated adsorption capacity and adsorption rate, mechanical properties, environmental adaptability and cyclic properties of porous TPU materials were studied.The results show that the TPU-8% porous monolithic material prepared by heat-induced phase separation method shows good performance when the polymer concentration is 8%, the phase separation temperature is 0°C, the phase separation time is 30min, and the mixing solvent ratio is 9:1.
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聚氨酯基多孔材料及其吸附性能研究
采用两步冷却的热诱导相分离法制备了柔性超疏水热塑性聚氨酯(TPU)多孔材料。深入讨论了制备工艺对材料微观结构的影响。详细分析了多孔TPU材料的微观结构、疏水性和比表面积。研究了多孔TPU材料的表面润湿性、分离选择性、饱和吸附量和吸附速率、力学性能、环境适应性和循环性能。结果表明,当聚合物浓度为8%、相分离温度为0℃、相分离时间为30min、混合溶剂比为9:1时,热诱导相分离法制备的TPU-8%多孔整体材料具有良好的性能。
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