Lattice vibration spectra of potassium lithium niobate single crystals

Y. Wan, S. Yoo, Qing Wang, Chu Junhao
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Abstract

The lattice vibration spectra of potassium lithium niobate (KLN) single crystals have been studied using Raman spectroscopy. The characteristic Raman peak due to the bend vibration mode of the [NbO/sub 6/]/sup 7-/ octahedra is split into three peaks as the Li ion content of the KLN crystal is increased, supporting that the vibration modes of the octahedrons are slightly perturbed by the bend vibration mode of Li in C-site.
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铌酸锂钾单晶晶格振动谱
利用拉曼光谱研究了铌酸锂钾(KLN)单晶的晶格振动谱。随着KLN晶体中Li离子含量的增加,由[NbO/sub 6/]/sup 7-/八面体的弯曲振动模式引起的特征拉曼峰分裂为三个峰,说明c位Li的弯曲振动模式对八面体的振动模式有轻微的扰动。
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