Effect of Organic Extractants on the Extraction of Rare Earth Elements from Sulphuric Acid Leach Liquor

Altansukh Batnasan, Ariunbolor Narankhuu, Ariuntuya Battsengel, Kazutoshi Haga, A. Shibayama
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Abstract

In this study, the various organic extractants, namely D2EHPA, PC-88A, TBP, TBPP, TOA, and TOPO, were examined to extract REEs from sulphuric acid leach liquor of apatite ore. Extraction parameters including extractants type, the concentration of extractant, organic to aqueous phase ratio, and contact time were investigated. Stripping experiments were conducted using different concentrations (0.5-4 M) of hydrochloric acid. Results showed that the overall extraction of REEs into the PC-88 extractant were ranged between 20 and 35%, while their extraction with other extractants did not exceed 20%. Interestingly, heavy rare earth elements (Tb, Dy, Er, and Y) were selectively extracted with D2EHPA when the light REEs extraction was lower than 5%.
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有机萃取剂对硫酸浸出液中稀土元素萃取的影响
研究了D2EHPA、PC-88A、TBP、TBPP、TOA、TOPO等多种有机萃取剂对磷灰石硫酸浸出液中稀土元素的萃取作用,考察了萃取剂类型、萃取剂浓度、有机水相比、接触时间等萃取参数。用不同浓度的盐酸(0.5 ~ 4 M)进行溶出实验。结果表明,PC-88萃取剂对稀土元素的总体提取率在20% ~ 35%之间,而其他萃取剂对稀土元素的提取率均不超过20%。有趣的是,当轻稀土的提取率低于5%时,D2EHPA可以选择性地提取重稀土元素(Tb、Dy、Er和Y)。
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