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Fabrication and Characterization of Copper Phthalocyanine- Based Field Effect Transistors 酞菁铜基场效应晶体管的制备与表征
N. Uranbileg, Tuul Tsagaantsooj, Anar Enkhbayar, Davaajargal Darambazar, Munkh-Erdene Erdene-Ochir, Ganzorig Chimed
Future generations of electronic products will be enabled by flexible electronic circuits, displays, and sensors based on organic active materials, which could eventually reach the mainstream electronics industry. One of such devices is the organic field-effect transistor (OFET), which are three-terminal devices that are comprised of a gate, source, and drain electrode. In this study, we fabricated a bottom-gate bottom-contact OFET device using copper phthalocyanine (CuPc) as a semiconducting layer. CuPc is a commercially available metal complex, a known p-type semiconducting material. Au/Ti electrode is sputtered on Al gated silicon substrate with thermally grown SiO2 dielectric layer. CuPc films were then deposited over the substrate with patterned electrodes by physical vapor deposition at a rate of 0.35 nm/s, recorded by a quartz crystal microbalance at room temperature under a background pressure of 1.21x10 Pa. A thin layer of organic material was also deposited on glass slides and the optical properties of films with different thicknesses were determined by UV-Vis spectrometry and the optical band-gap energy was determined to be 1.64±0.01 eV. The thermal annealing effect on thin-film crystallization morphology was studied with atomic force microscopy (AFM) and contact angle measurement.
未来几代电子产品将由基于有机活性材料的柔性电子电路、显示器和传感器实现,最终将进入主流电子产业。其中一种器件是有机场效应晶体管(OFET),它是由栅极、源极和漏极组成的三端器件。在本研究中,我们以酞菁铜(CuPc)为半导体层,制作了一个底栅底接触OFET器件。CuPc是一种商业上可用的金属复合物,一种已知的p型半导体材料。Au/Ti电极溅射在Al门控硅衬底上,衬底上有热生长的SiO2介电层。在1.21x10 Pa的背景压力下,以0.35 nm/s的速率,通过石英晶体微天平在室温下记录CuPc薄膜的物理气相沉积。在玻片上沉积了一层薄薄的有机材料,用紫外-可见光谱法测定了不同厚度薄膜的光学性能,测得其带隙能为1.64±0.01 eV。利用原子力显微镜(AFM)和接触角测量研究了热退火对薄膜结晶形貌的影响。
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引用次数: 0
Effect of Organic Extractants on the Extraction of Rare Earth Elements from Sulphuric Acid Leach Liquor 有机萃取剂对硫酸浸出液中稀土元素萃取的影响
Altansukh Batnasan, Ariunbolor Narankhuu, Ariuntuya Battsengel, Kazutoshi Haga, A. Shibayama
In this study, the various organic extractants, namely D2EHPA, PC-88A, TBP, TBPP, TOA, and TOPO, were examined to extract REEs from sulphuric acid leach liquor of apatite ore. Extraction parameters including extractants type, the concentration of extractant, organic to aqueous phase ratio, and contact time were investigated. Stripping experiments were conducted using different concentrations (0.5-4 M) of hydrochloric acid. Results showed that the overall extraction of REEs into the PC-88 extractant were ranged between 20 and 35%, while their extraction with other extractants did not exceed 20%. Interestingly, heavy rare earth elements (Tb, Dy, Er, and Y) were selectively extracted with D2EHPA when the light REEs extraction was lower than 5%.
研究了D2EHPA、PC-88A、TBP、TBPP、TOA、TOPO等多种有机萃取剂对磷灰石硫酸浸出液中稀土元素的萃取作用,考察了萃取剂类型、萃取剂浓度、有机水相比、接触时间等萃取参数。用不同浓度的盐酸(0.5 ~ 4 M)进行溶出实验。结果表明,PC-88萃取剂对稀土元素的总体提取率在20% ~ 35%之间,而其他萃取剂对稀土元素的提取率均不超过20%。有趣的是,当轻稀土的提取率低于5%时,D2EHPA可以选择性地提取重稀土元素(Tb、Dy、Er和Y)。
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引用次数: 0
Thermal Solvolysis of Coals Under Mild Conditions as an Alternative Way to Produce Aromatics for Carbon Materials 温和条件下煤的热溶解法制备碳材料芳烃的替代方法
P. Kuznetsov, B. Avid, L. Kuznetsova, B. Purevsuren, X. Fan, Z. Ismagilov, V. Safin
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引用次数: 0
Microbiological and Hydrochemical Parameters of Deep Wells Used for Drinking Water in Ulaanbaatar, Mongolia 蒙古乌兰巴托饮用水深井微生物学及水化学参数
D. Ganpurev, Odontuya Gombosuren, Tsiiregzen Andarai, D. Battulga, Ichinnorov Amarjargal, Buyanjargal Zolboot, Khureldavaa Otgonbayar, Oyuntsetseg Dolgorjav, Amarsanaa Badgaa
Groundwater is not a nutrient-rich environment for microorganisms to grow and thrive, but it is polluted by many environmental factors. These nutrients can exceed the permissible levels in drinking water and can be a reason for spreading highly infectious diseases in the population. Therefore, there is a need to monitor the quality of water from deep wells in ger areas, to study certain correlations, to prevent people from various infectious diseases, to protect the environment, to use water resources properly, and to provide citizens with accurate information on drinking water. Within the framework of the study, samples were taken from 135 deep wells used for drinking and household purposes in the Bayanzurkh, Bayangol, and Sukhbaatar districts of Ulaanbaatar city. The water quality was analyzed for some hydrochemical (NO3 ) and six main microbiological parameters. Due to microbiological parameters, 42 samples (30.6%) from the surveyed deep wells did not meet the requirements of MNS 0900:2018, the national drinking water standard of Mongolia, and 31 samples (21.9%) exceeded the nitrate ion content described in above the standard. In the Bayangol district, 88% of the surveyed sources found that the number of bacterial contaminants in 100 mL of water exceeded the limit. But in the Sukhbaatar district’s summer camp region which is a relatively low populated area was shown a relatively low level of microbiological contamination and nutrient pollution compared to the permissible level in water samples. According to correlation studies, the nitrate ion concentrations of 12.6% samples over the permissible value (more than 50 mg/L) and high level of bacterial contamination in drinking water, showed a weak correlation.
地下水不是微生物生长和繁衍的营养丰富的环境,但受到多种环境因素的污染。这些营养物质在饮用水中可能超过允许的水平,并可能成为高度传染性疾病在人群中传播的一个原因。因此,有必要监测ger地区深井的水质,研究某些相关性,防止人们患上各种传染病,保护环境,正确使用水资源,并向公民提供有关饮用水的准确信息。在研究框架内,样本取自乌兰巴托市巴扬祖尔克、巴扬戈尔和苏赫巴托尔地区135口用于饮用和家庭用途的深井。对水质进行了水化学(NO3)和6个主要微生物参数的分析。受微生物参数影响,调查深井中有42份样品(30.6%)不符合蒙古国家饮用水标准MNS 090:2018要求,31份样品(21.9%)硝酸盐离子含量超标。在巴彦古尔区,88%的调查来源发现100毫升水中的细菌污染物数量超过了限制。但在人口相对较少的苏赫巴托尔地区的夏令营区与水样中的允许水平相比微生物污染和营养物污染水平相对较低。根据相关性研究,12.6%的样品硝酸盐离子浓度超过允许值(超过50 mg/L)与高水平的饮用水细菌污染呈弱相关性。
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引用次数: 0
The Characterization of Acid Soluble Collagen from Sheep Tail Tendon 羊尾腱酸溶性胶原蛋白的表征
Budjav Jadamba, Enerelt Urnukhsaikhan, Anujin Gantulga, Sugar Lkhagvachuluun, E. Lkhagvasuren, Bilegtsaikhan Tsolmon, Lkhagvasuren Damdindorj
The sheep (Ovis aries) tail tendons are the major by-products after being slaughtered for food consumption. A tendon is a powerful band of fibrous connective tissue that is composed of parallel bundles of collagen fibers and connects muscle to bone, due to the transmit forces and tolerate tension during muscle contraction. The tendon collagen structure is found as the main molecule of dense fibrous tissue and forms approximately 70% of dry weight. The collagen type is largely composed of Type I (60%) and other types. Type I collagen is by far the most abundant molecules in vertebrates, and it is a particularly mechanical scaffold in bone, skin, and connective tissue. This study was conducted to extract and characterize acid-soluble collagens (ASC) from sheep tail tendons. The tendon collagen was confirmed as collagen by different physicochemical techniques such as sodium dodecyl sulfate-polyacrylamide gel electrophoresis (SDS-PAGE), Zeta Potential Analyzer, and Fourier transform infrared (FTIR) spectra analysis. The yield of type I ASC from sheep tail tendon was about 9.7% on the dry weight of raw material. The collagen’s α1, α2, and β chain bands are observed in SDS-PAGE for both ASC and pepsin soluble collagen. The zeta potentials of ASC had a positive charge when pH from 2 to 4.5, while the negative charge in pH range from 6 to 11. But the electric potential of ASC was zero at pH 5. The results of FTIR spectra analysis detected the presence of triple superhelical structure in acid-soluble collagens, presenting isolation procedure did not interrupt the triple helical structure from the sheep tail tendon. Therefore, the study showed that it is a potential reference for collagen extraction and application of sheep tendon tails.
绵羊(Ovis aries)的尾筋是屠宰食用后的主要副产品。肌腱是一种强大的纤维结缔组织,由平行的胶原纤维束组成,由于肌肉收缩时的传递力和承受张力,它将肌肉与骨骼连接起来。肌腱胶原蛋白结构是致密纤维组织的主要分子,约占干重的70%。胶原蛋白类型主要由I型(60%)和其他类型组成。到目前为止,I型胶原蛋白是脊椎动物中含量最多的分子,它是骨骼、皮肤和结缔组织中特别机械的支架。本研究旨在从羊尾肌腱中提取酸溶性胶原蛋白,并对其进行鉴定。采用十二烷基硫酸钠-聚丙烯酰胺凝胶电泳(SDS-PAGE)、Zeta电位分析仪和傅里叶变换红外(FTIR)光谱分析等理化方法证实了肌腱胶原蛋白的存在。以羊尾腱为原料,产率约为原料干重的9.7%。SDS-PAGE均观察到ASC和胃蛋白酶可溶性胶原的α1、α2和β链带。pH值为2 ~ 4.5时,ASC的zeta电位带正电荷,pH值为6 ~ 11时,ASC的zeta电位带负电荷。但在ph5时ASC的电势为零。FTIR光谱分析结果显示,酸溶性胶原蛋白中存在三螺旋结构,表明分离过程并未中断羊尾腱的三螺旋结构。因此,本研究为羊腱尾胶原蛋白的提取和应用提供了潜在的参考。
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引用次数: 1
Cu(II), Pb(II) and Cr(VI) Adsorption on the Modified Activated Carbon 改性活性炭对Cu(II)、Pb(II)和Cr(VI)的吸附
Nasanjargal Shirendev, Munkhpurev Bat-Amgalan, A. Aleksandr, Burmaa Gunchin, Ganchimeg Yunden
In this study, the sorptions of Cu(II), Pb(II), and Cr(VI) on amine-functionalized activated carbon were investigated. Coal from the Tavantolgoi deposit of Mongolia was used as a precursor for the modification. After the coal carbonization, the char was activated with heated steam at different times (120, 180, and 240 min) and several temperatures (800oC and 850oC). The activated carbon at 850oC for 240 min was used for the treatment with 3-aminopropyltriethoxysilane (APTES). The interactions between metal ions and functional groups on the sorbent surface were confirmed by Fourier transform infrared (FT-IR) spectroscopy, scanning electron microscopy (SEM) coupled with X-ray energy dispersive spectroscopy (EDS). The influence of various parameters such as pH (2-7), contact time (0.5-6 h), temperature (25oC, 35oC, 45oC, and 55oC), initial concentration of heavy metals ions (10, 25, and 50 mg/L), and common cations (Na, K, Ca, Mg) was investigated. The optimum pH for Cu(II), Pb(II), and Cr(VI) sorption on the modified activated carbon was chosen as 4, 3, and 3, respectively. The sorption capacity was increased from 6.15 to 9.88 mg/g and 17.1 mg/g to 19.0 mg/g when increased the temperature from 25oC to 55oC for Cu(II) and Cr(VI) adsorption, respectively (initial concentration of metal ions were 50 mg/L). But the sorption capacity was decreased from 3.13 mg/g to 2.69 mg/g when increased the temperature from 25oC to 55oC for Pb(II) adsorption. The thermodynamic parameters such as enthalpy (ΔHo), entropy (ΔSo), and Gibb’s free energy (ΔGo) were estimated, and the results confirmed that all sorption processes are spontaneous and thermodynamically favorable. The sorption capacity was decreased when the amount of Na, K, Ca, or Mg increased from 0 to 200 mg/L, and a remarkable decrease in sorption capacity was observed for Pb(II) adsorption. The order of adsorption capacity of modified activated carbon for metal ions was Cr(VI) Cu(II) Pb(II). The sorption mechanism was discussed for the
研究了氨基功能化活性炭对Cu(II)、Pb(II)和Cr(VI)的吸附性能。以蒙古Tavantolgoi矿床的煤为前驱体进行改性。煤炭化后,在不同时间(120min、180min、240min)和不同温度(800oC、850oC)下用加热蒸汽活化焦炭。活性炭在850℃、240 min条件下用3-氨基丙基三乙氧基硅烷(APTES)处理。利用傅里叶变换红外光谱(FT-IR)、扫描电镜(SEM)和x射线能量色散光谱(EDS)验证了金属离子与吸附剂表面官能团的相互作用。考察了pH值(2 ~ 7)、接触时间(0.5 ~ 6 h)、温度(25℃、35℃、45℃、55℃)、重金属离子初始浓度(10、25、50 mg/L)和常见阳离子(Na、K、Ca、mg)等参数的影响。改性活性炭吸附Cu(II)、Pb(II)和Cr(VI)的最佳pH分别为4、3和3。当温度从25℃提高到55℃时,Cu(II)和Cr(VI)的吸附量分别从6.15 mg/g提高到9.88 mg/g和17.1 mg/g提高到19.0 mg/g(金属离子初始浓度为50 mg/L)。当温度由25℃升高至55℃时,吸附量由3.13 mg/g下降至2.69 mg/g。热力学参数如焓(ΔHo)、熵(ΔSo)和吉布自由能(ΔGo)进行了估计,结果证实了所有吸附过程都是自发的,热力学有利。当Na、K、Ca、Mg的吸附量从0 ~ 200 Mg /L增加到200 Mg /L时,吸附量下降,对Pb(II)的吸附量明显下降。改性活性炭对金属离子的吸附量大小顺序为Cr(VI) Cu(II) Pb(II)。讨论了其吸附机理
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引用次数: 0
Beneficiation and Sulfuric Acid Leaching of Manganese Ore 锰矿石的选矿及硫酸浸出
Sukhbat Sandag-Ochir, Zagarzusem Tsedendamba, Orgilbayar Batkhuyag, Jargalsaikhan Lkhasuren, Khasbaatar Dashkhuu, Sugir-Erdene Namsrai, Baasanjav Dashtseren, Unursaikhan Buyannasan, Otgonjargal Enkhtur
The beneficiation of low-grade manganese ore is investigated using applied magnetics separation, multi-gravity separator, shaking table, flotation methods, and sulfuric acid leaching. The manganese content in the ore sampled from the Unagad deposit is 17.31%. The best option and high result among beneficiation experiments is the use of a multi-gravity separator. Manganese leaching from the concentrate is investigated using H2SO4 and H2O2 as leaching and reducing agents. A study on the characterization of the main parameters such as agitation, reaction temperature, leaching time, H2SO4 concentration, H2O2 concentration, and liquid/solid mass ratio for increasing leaching of the manganese from the beneficiated samples was performed. The optimal leaching efficiency was 86.79% for manganese.
采用应用磁选、重选、摇床、浮选、硫酸浸出等方法对某低品位锰矿石进行了选矿试验研究。Unagad矿床样品中锰含量为17.31%。在选矿试验中,采用多重分选机是最佳选择,效果好。以H2SO4和H2O2为浸出剂和还原剂,研究了该精矿中锰的浸出。研究了搅拌、反应温度、浸出时间、H2SO4浓度、H2O2浓度、液固比等主要参数对提高选矿样品中锰的浸出率的影响。锰的最佳浸出率为86.79%。
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引用次数: 0
Waterflooding Technique to the Kashkari Oilfield in the North Part of Afghanistan 阿富汗北部Kashkari油田注水技术研究
Zabihullah Mahdi, Kazunori Abe, Khwaja Naweed Seddiqi, Hikari Fujii
Hydrocarbons represent an important natural resource for the rehabilitation and sustainable development of Afghanistan. In this paper, the use of waterflooding is demonstrated for the petroleum reservoirs of the Kashkari oilfield in northern Afghanistan. The technique stands on the Buckley–Leverett frontal-displacement theory, which enables computation of the progress of the waterfront in the reservoir. The oil and water relative permeabilities, the irreducible water saturation, and the residual oil saturation are obtained from a laboratory experiment. The technique is conducted to the Kashkari oilfield to predict the feasible quantity of the oil that could be produced from this reservoir. As a result, the Buckley–Leverett waterflooding technique recovered 67 MMBBL oil of Kashkari oilfield in 6200 days.
碳氢化合物是阿富汗复兴和可持续发展的重要自然资源。本文以阿富汗北部Kashkari油田为例,对水驱的应用进行了论证。该技术基于巴克利-莱弗里特锋面位移理论,可以计算水库中滨水的进度。通过室内实验获得了油水相对渗透率、不可还原水饱和度和剩余油饱和度。将该技术应用于喀什卡里油田,以预测该油藏的可行产油量。结果,Buckley-Leverett水驱技术在6200天内回收了Kashkari油田6700万桶原油。
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引用次数: 0
The Physicochemical Composition of Sea Buckthorn (Hippophae rhamnoides L) Oil and Its Treatment Characteristics 沙棘(Hippophae rhamnoides L)油的理化成分及其处理特性
Bayarmaa Barkhuu, Munkhgerel Lodonjav, Oyundari Ganzorig, Nomindari Tumurtogoo
Sea buckthorn ( Hippophae rhamnoides L.) oil is a unique oil source, emphasizing its potential as a dietary and medicinal supplement. Many studies have shown that the whole berry oil of sea buckthorn is rich in saturated and unsaturated fatty acids and fat-soluble vitamins. The oil also had been used in digestive ulcers and cardiovascular disease. The present study has determined the whole berry oil of sea buckthorn physicochemical parameters, such as refractive index, acid value, iodine value and peroxide value, and fatty acid composition. The dominating fatty acids in whole berry oil were oleic, linoleic, and linolenic. Also, the therapeutic properties of whole berry oil and its acute and chronic toxicity were determined. In addition, we carried out the pharmacological effect of the whole berry oil of sea buckthorn on indomethacin-induced gastric ulcers in rats. It has been shown that sea buckthorn oil positively affects the regeneration of stomach tissues in experimental rats in case of stomach ulcers. However, the bacterial mass in the mucous membranes of the stomach in some rats was increased.
沙棘(Hippophae rhamnoides L.)油是一种独特的油源,强调其作为膳食和药用补充剂的潜力。许多研究表明,沙棘全果油含有丰富的饱和和不饱和脂肪酸以及脂溶性维生素。这种油还被用于治疗消化性溃疡和心血管疾病。本研究测定了沙棘全果油的折射率、酸值、碘值和过氧化值以及脂肪酸组成等理化参数。全莓油中的主要脂肪酸是油酸、亚油酸和亚麻酸。并对全莓油的治疗作用及其急性和慢性毒性进行了测定。此外,我们还研究了沙棘全莓油对消炎痛致大鼠胃溃疡的药理作用。研究表明,沙棘油对实验性胃溃疡大鼠的胃组织再生有积极的影响。但部分大鼠胃粘膜细菌量增加。
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引用次数: 2
Hydrocracking of Atmospheric Residue from Tsagaan-Els Oil, Mongolia 蒙古察坎-埃尔斯石油常压渣油加氢裂化研究
Myagmargerel Bayanmunkh, Byambajav Ganbold, Narangerel Janchig, Gantsetseg Byambasuren, Khulan Bayasgalan
Cracking is the complex physical and chemical process of converting high molecular hydrocarbons into valuable products such as gasoline fraction and light fuel fraction. There are several oil fields in Mongolia and three large deposits already are being exploited. The crude oil was classified as high-paraffinic crude oil because of its high viscosity and low yield of fuel fraction. The contents of asphaltenes and resins in the oil were low. Therefore, the cracking process is necessary to convert the paraffinic Mongolian crude oil to lighter distillates for the production of transportation fuels and chemicals. In this work, we studied the hydrocracking process of atmospheric residue (>350°C) to produce fuel fractions from high paraffin Tsagaan-Els oil of Mongolia. The hydrocracking experiment was carried out with and without a catalyst at temperature 450°C for 1-3 h under a hydrogen pressure of 5 MPa. Commercial Ni-Mo/Al2O3 catalyst (Ni 3%, Mo 15%) was used in the hydrocracking experiments for 1 and 2 h. The yields of light and middle distillates obtained by hydrocracking of the atmospheric residue for 3 h without catalyst were 15.8 and 17.7 wt.%, respectively. The effect of catalyst was tested in the experiments for 2 h. By the hydrocracking with catalyst, the yield of light distillate has increased 4.5 wt.% in comparison with the yield of light distillate obtained from the experiment without catalyst. In this study, we report that the atmospheric residue in the Tsagaan-Els oil could be liquefied by thermal cracking at 350°C to increase the yield of gasoline and diesel fuel.
裂解是将高分子烃转化为汽油馏分和轻质燃料馏分等有价值产品的复杂物理化学过程。蒙古有几个油田,有三个大型油田正在开采中。该原油因其高粘度、低馏分收率而被归为高石蜡原油。油中沥青质和树脂含量较低。因此,将含石蜡的蒙古原油转化为用于生产运输燃料和化工产品的轻质馏分油是必要的。本文研究了常压渣油(>350℃)加氢裂化生产高石蜡蒙古tsagaan - el石油馏分的工艺。在温度450℃、氢气压力5 MPa条件下,加氢裂化实验分别进行了加氢裂化和无催化剂加氢裂化实验。采用Ni-Mo/Al2O3催化剂(Ni为3%,Mo为15%)加氢1 h和2 h,无催化剂常压渣油加氢3 h,轻馏分和中馏分收率分别为15.8%和17.7% wt.%。在2 h的加氢实验中考察了催化剂的作用。有催化剂加氢裂化后,轻馏分得率比无催化剂加氢裂化时提高了4.5 wt.%。在这项研究中,我们报告了tsagaan - el油中的大气残渣可以在350°C下进行热裂解液化,以提高汽油和柴油的产量。
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引用次数: 0
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Proceedings of the 5th International Conference on Chemical Investigation and Utilization of Natural Resource (ICCIUNR-2021)
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