A Modeling Study of Operating Conditions and Different Supports on Fe-Co-Ce Nanocatalyst and Optimizing of Light Olefins Selectivity in the Fischer-Tropsch Synthesis

IF 1 Q4 CHEMISTRY, MULTIDISCIPLINARY Chemistry & Chemical Technology Pub Date : 2021-06-15 DOI:10.23939/CHCHT15.02.170
T. Lari, P. O. B. Z. I. Baluchestan, A. Mirzaei, H. Atashi, H. Bozorgzadeh
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Abstract

This study demonstrates the effect of operating conditions (Red-GHSV, inlet H2/CO, Oprat-GHSV) and the effect of Fe-Co-Ce nanocatalyst support. A statistical model using the response surface methodology (RSM) was applied with the target of achieving higher olefins selectivity in Fischer-Tropsch synthesis, which indicates the interaction effects of factors. The conditions under which three objectives optimization for maximizing olefins and minimizing paraffins and methane were determined. Synthesized nanocatalysts with various supports were characterized by XRD, SEM and TPR techniques
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Fe-Co-Ce纳米催化剂操作条件和不同载体的模拟研究及费托合成中轻烯烃选择性的优化
本研究考察了操作条件(Red-GHSV、进口H2/CO、operat - ghsv)和Fe-Co-Ce纳米催化剂负载的影响。以在费托合成中获得更高的烯烃选择性为目标,采用响应面法(RSM)建立了统计模型,表明了各因素的交互作用。确定了烯烃最大化、烷烃最小化和甲烷最小化三个优化目标的条件。采用XRD、SEM和TPR技术对不同载体合成的纳米催化剂进行了表征
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来源期刊
Chemistry & Chemical Technology
Chemistry & Chemical Technology CHEMISTRY, MULTIDISCIPLINARY-
CiteScore
1.70
自引率
44.40%
发文量
60
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