Mechanical Properties and Damage Behaviours of Polyurethane Composites Reinforced With BNNP and MWCNT Hybrid Nanoparticles

Gülay Bahtiyar, M. Ekrem, B. Ünal, Safa Ak
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Abstract

In recent years, with increasing engineering applications, structural adhesives have played an increasingly important role in joining both metallic and non-metallic components. Polyurethane is frequently used in the adhesive industry due to its morphological structure, versatile material, and excellent matrix material. In addition, by doping polyurethane with single/multi-walled carbon nanotubes and boron nitride nanoplates materials, the mechanical properties of the polyurethane adhesive can be further increased. This study aimed to increase the mechanical properties of PU (thermoset polyurethane), which is frequently used in adhesively bonded joints by addition of MWCNT (multi-walled carbon nanotubes), BNNP (boron nitride nanoplates). For this purpose, nanoparticles synergistic interaction was investigated by adding a mass of 0.25%, 0.35%, and 0.45% MWCNT into PU, which was reinforced by 0.5% BNNP before. Samples mechanical properties were determined by tensile test according to ASTM D638-10 standard, flexure test according to ASTM D790-02 standard, and Shore D test according to ASTM D2240 standard. All sample test results were graphed, and each graph was compared. Also, broken surfaces were analyzed by scanning electron microscopy (SEM) to examine the damage mechanism of nanoparticles.
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BNNP和MWCNT复合纳米颗粒增强聚氨酯复合材料的力学性能和损伤行为
近年来,随着工程应用的不断增加,结构胶粘剂在连接金属和非金属构件方面发挥着越来越重要的作用。聚氨酯由于其形态结构、材料用途广泛、基体材料优良等优点,在胶粘剂工业中得到了广泛的应用。此外,通过在聚氨酯中掺杂单/多壁碳纳米管和氮化硼纳米片材料,可以进一步提高聚氨酯胶粘剂的力学性能。本研究旨在通过添加多壁碳纳米管(MWCNT)和氮化硼纳米板(BNNP)来提高粘接接头中常用的热固性聚氨酯(PU)的力学性能。为此,研究了纳米颗粒的协同作用,分别在PU中添加0.25%、0.35%和0.45%的MWCNT,并在PU中添加0.5% BNNP增强。按ASTM D638-10标准进行拉伸试验,按ASTM D790-02标准进行弯曲试验,按ASTM D2240标准进行Shore D试验。将所有样品检测结果绘制成图表,并对每个图表进行比较。同时,利用扫描电子显微镜(SEM)对破碎表面进行分析,探讨纳米颗粒的损伤机理。
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