Synthesis of hexahydroxy strontium stannate nanorods for photocatalytic degradation of organic pollutants

Z. Xue, F. Y. Li, C. Yu, J. F. Huang, F. Tao, Z. Cai, L. Pei
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引用次数: 5

Abstract

Abstract Hexahydroxy strontium stannate nanorods were synthesized via a facile hydrothermal route and characterized by X-ray diffraction, electron microscopy, X-ray photoelectron spectroscopy and solid UV-Vis diffuse reflectance spectroscopy. The nanorods with single crystalline hexagonal SrSn(OH)6 phase have lengths of several μm and diameters of 50–150 nm. The formation process was investigated by observing the evolution of the morphology and structure under different conditions. The band gap is 3.76 eV. The photocatalytic performance of the nanorods was evaluated under ultraviolet light irradiation with crystal violet in aqueous solution which can be entirely photo-degraded within 6 hours. Anti-interference experiments showed that hydroxyl radicals, holes, and superoxide radicals are involved in the sdegradation of crystal violet.
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光催化降解有机污染物的六羟基锡酸锶纳米棒的合成
摘要采用简单的水热法合成了六羟基锡酸锶纳米棒,并用x射线衍射、电子显微镜、x射线光电子能谱和固体UV-Vis漫反射光谱对其进行了表征。单晶六方SrSn(OH)6相纳米棒的长度为几μm,直径为50 ~ 150 nm。通过观察不同条件下的形貌和结构演变来研究其形成过程。带隙为3.76 eV。用结晶紫在紫外光照射下评价了纳米棒的光催化性能,并在6小时内完全光降解。抗干扰实验表明,羟基自由基、空穴和超氧自由基参与了结晶紫的降解。
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