Eletroless Silver Coated Nanocenosphere/Polymer Composite for EMI Shielding Effectiveness

S. Vynatheya, B. Raju, L. Chandrasagar, Sushma Us
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Abstract

Electromagnetic interference (EMI) is an escalating concern in the modern electronic climate. As such it has become a critical area to consider when designing and packaging electronics. In this context, Electroless Silver Coated nanocenosphere (SCNC) in Poly Methyl Methacrylate (PMMA) and Acrylonitrile Butadiene Styrene (ABS) composites has been tried for its EMI shielding effectiveness. The strategy is to render the polymer conductive by dispersing SCNC in various proportions in these polymers separately and to promote wave absorption by making sheet of the polymer-based composite. In our study EDX (Energy Dispersive X-Ray) analysis confirmed the presence of Ag on the coated nano cenosphere. This was further, confirmed through Phase analysis by XRD (X-Ray Diffractometer) analysis. SEM (Scanning Electron Microscope) analysis was conducted to see the size, shape and adherence of the Ag coating on nanoenosphere particles and to observe the distribution of these particles in polymer matrix in the composite sheet. BET Surface area of electroless coated powders was quite high indicating good surface properties. The processing methods, electrical properties (surface resistivity) and electromagnetic behavior (EMI shielding effectiveness) were investigated. Shielding effectiveness (SE) values of approximately 25 dB at a frequency of 1 GHz was obtained for coatings of Electroless Silver coated nanocenospheres in ABS polymer which was further increased by adding other conductive nano fillers (Graphene and multi walled Carbon Nano tube) along with coated nanocenospheres.
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化学镀银纳米微球/聚合物复合材料的电磁干扰屏蔽效果
电磁干扰(EMI)是现代电子环境中日益受到关注的问题。因此,它已成为设计和包装电子产品时要考虑的关键领域。在此背景下,对聚甲基丙烯酸甲酯(PMMA)和丙烯腈-丁二烯-苯乙烯(ABS)复合材料中的化学镀银纳米微球(SCNC)的电磁干扰屏蔽效果进行了试验。该策略是通过在这些聚合物中分别分散不同比例的SCNC来使聚合物导电,并通过制作聚合物基复合材料片来促进波吸收。在我们的研究中,EDX(能量色散x射线)分析证实了银在涂层纳米空心球上的存在。通过XRD (x射线衍射仪)分析进一步证实了这一点。通过SEM(扫描电子显微镜)分析了银涂层在纳米微球颗粒上的大小、形状和粘附情况,并观察了纳米微球颗粒在复合片中聚合物基体中的分布情况。化学涂覆粉末的表面积相当高,表明其具有良好的表面性能。研究了材料的加工方法、电学性能(表面电阻率)和电磁性能(电磁干扰屏蔽效能)。在1 GHz频率下,ABS聚合物中化学镀银纳米微球涂层的屏蔽效能(SE)值约为25 dB,通过在涂层纳米微球中添加其他导电纳米填料(石墨烯和多壁碳纳米管)可以进一步提高屏蔽效能。
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