PHYSICO-CHEMICAL FOUNDATIONS OF INNOVATIVE TECHNOLOGIES IN THE FIELD OF PHOTOCATALYSIS

A. Djenyuk, M. Sakhnenko, H. Karakurkchi, A. Galak, S. Indykov, Gulmira Yar-Mukhamedova
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Abstract

An analysis of the physical and chemical foundations of the synthesis of photocatalytic materials on metal platforms was carried out in terms of the restructuring of the country's industrial production according to the new Industry 4.0 paradigm. Possible ways to improve the functional properties of such materials are determined using titanium dioxide as the most effective and accessible material for creating photocatalysts by doping with non-metal and metal compounds or creating composites and non-stoichiometric oxides as an example. A variant way of creating heterooxide composites by inversion of the elements of the structure-forming matrices and the strengthening phase is proposed. A detailed analysis of the problems arising during the surface treatment of high-alloy valve metal alloys by electrochemical technologies is given, and directions for solving such problems due to the homogenization of the surface layers of the processed materials are determined. A technological scheme for the implementation of such a methodology for variable scenarios using plasma-electrolyte oxidation is proposed. The difference in the electrochemical characteristics of heterooxide composites depending on the nature of the dopants was established, which is fully consistent with the nature of the latter.
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光催化领域创新技术的物理化学基础
根据新的工业4.0范式,根据国家工业生产的重组,对金属平台上光催化材料合成的物理和化学基础进行了分析。以二氧化钛为例,通过掺杂非金属和金属化合物或制造复合材料和非化学计量氧化物来制造光催化剂,以二氧化钛作为最有效和最容易获得的材料,确定了改善此类材料功能特性的可能方法。提出了一种通过结构形成基体和强化相元素的反转来制备异质复合材料的方法。详细分析了利用电化学技术对高合金阀门金属合金进行表面处理过程中出现的问题,并确定了处理材料表层均质化问题的解决方向。提出了一种技术方案,用于实现这种方法的可变场景使用等离子体电解质氧化。建立了杂氧化物复合材料的电化学特性随掺杂物性质的不同而不同,这与杂氧化物复合材料的性质完全一致。
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