Broad-band dielectric spectroscopy of some alcohols down to the glass transition temperature Tg

L. de Francesco, M. Cutroni, A. Mandanici
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引用次数: 4

Abstract

Abstract The dielectric spectroscopy technique has been used over a broad-band range of frequencies to compare the dynamic response of some supercooled liquids down to the glass transition temperature Tg . Glycerol, 1,2-propanediol and 2,3-butanediol have been chosen because they differ in both their chain lengths, that is the number of carbon atoms, and their hydroxyl groups OH. The frequency and temperature dependences of the real and imaginary parts of the dielectric permittivity seem to be correlated to the structure of the molecules.
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一些醇的宽频带介电光谱下降到玻璃化转变温度Tg
在较宽的频率范围内,利用介电光谱技术比较了一些过冷液体在玻璃化转变温度Tg下的动态响应。选择甘油,1,2-丙二醇和2,3-丁二醇是因为它们的链长,也就是碳原子的数目,和羟基都不同。介电常数的实部和虚部的频率和温度依赖性似乎与分子的结构有关。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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