Comparison of Dielectric Properties of Low-density Polyethylene/MgO Composites with Different Size Fillers

K. Ishimoto, T. Tanaka, Y. Ohki, Y. Sekiguchi, Y. Murata, M. Gosyowaki
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引用次数: 28

Abstract

Two kinds of low-density polyethylene (LDPE) composites were prepared by adding semi-spherical MgO fillers different in diameter, one being around several ten nm and the other being several mum, and their dielectric properties were compared. At all the measurement temperatures, the conductivity is decreased and the permittivity is increased by the addition of fillers, irrespective of their sizes. However, the conductivity decrease is more significant and the permittivity increase is suppressed more in the case of the nm fillers. In addition, a drastic increase in dielectric loss factor at low frequencies is suppressed more significantly by the addition of the nm fillers. While the formation of packet-like charge observed in LDPE, which is assumed to appear at the front of the high-conductivity region that proceeds from one electrode toward the counter one, is suppressed significantly by both fillers, the effect is more significant in the nanocomposites. This means that the nanofillers suppress the increase in conductivity induced by the voltage application more effectively.
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不同粒径填料的低密度聚乙烯/氧化镁复合材料介电性能比较
通过添加直径不同的半球形MgO填料,制备了两种低密度聚乙烯(LDPE)复合材料,一种为几十nm左右,另一种为几nm,并比较了它们的介电性能。在所有测量温度下,通过添加填料,无论其大小如何,电导率都会降低,介电常数都会增加。而纳米填料的电导率下降更明显,介电常数的增加受到更大的抑制。此外,在低频时介质损耗因子的急剧增加被nm填料的加入更显著地抑制。虽然在LDPE中观察到的包状电荷的形成(假设出现在从一个电极到反一个电极的高导电性区域的前部)被两种填料显著抑制,但这种影响在纳米复合材料中更为显著。这意味着纳米填料更有效地抑制了电压施加引起的电导率的增加。
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