Preparation of Palm Fatty Acid Distillate (PFAD) As Raw Material for Bio Aviation Fuel Production

B. Wiethoff, Evita H. Legowo, D. Widiputri
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Abstract

Nowadays, aviation sector became one of the most important transportation in the world. The demand in this sector has increased rapidly over the last 10 years. Unfortunately, the increase of the demand leads to an increase of fuel consumption and CO2 emission in the aviation’s sector. Bio-based aviation fuel is believed to be one of the solution for the reduction of CO2 emission in the aviation’s sector. Palm Fatty Acid Distillate (PFAD) which is a by product of palm oil refinery, contains a high amount of free fatty acids. The free fatty acids contained in the PFAD are able to be converted into straight hydrocarbon chain through decarboxylation process. This thesis conducted 3 different experiments to find out the best decarboxylation reaction’s condition to convert the FFA into straight chain hydrocarbons over an activated carbon catalyst. The experiments compared the results between the experiment with different reaction’s conditions and the presence of solvent in the reaction. The results have shown that the third experiment, which used heptane as solvent and hydrogen in argon gas as reaction’s environment, has the best reaction’s condition among others. Experiment 3 has converted 77.07% of the FFA, while experiment 2 and 1 only converted 58.37% and 16.30% respectively.
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棕榈脂肪酸馏出物(PFAD)制备生物航空燃料原料
如今,航空业已成为世界上最重要的运输方式之一。在过去10年里,这一领域的需求迅速增长。不幸的是,需求的增加导致航空部门燃料消耗和二氧化碳排放的增加。生物基航空燃料被认为是减少航空部门二氧化碳排放的解决方案之一。棕榈脂肪酸馏出物(PFAD)是棕榈油精炼厂的副产品,含有大量的游离脂肪酸。PFAD中所含的游离脂肪酸可以通过脱羧过程转化为直烃链。本文通过3个不同的实验,找出在活性炭催化剂上将FFA转化为直链烃的最佳脱羧反应条件。实验将不同反应条件下的实验结果与反应中溶剂的存在进行了比较。结果表明,以庚烷为溶剂,氩气中的氢气为反应环境的实验三反应条件最好。实验3的FFA转化率为77.07%,而实验2和实验1分别仅为58.37%和16.30%。
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