{"title":"Hydrodenitrogenation of carbazole on alumina-supported molybdenum nitride catalyst","authors":"M. Nagai, T. Miyao, S. Omi","doi":"10.1201/9781482273540-19","DOIUrl":null,"url":null,"abstract":"This paper reports an experimental study of hydrodenitrogenation, at 330-350 °C and 50-150 atm total pressure, of carbazole on alumina-supported molybdenum nitride catalyst. The kinetics of C-N hydrogenolysis is analyzed to obtain rate expression for C-N hydrogenolysis which is a rate-determining step in equilibrium of the hydrogenation. Rate equations of the Langmuir-Hinshelwood type were compared with the rate dat using a non-linear leat-squares regression technique.","PeriodicalId":20402,"journal":{"name":"Preprints-American Chemical Society Division of Petroleum Chemistry","volume":"3 1","pages":"577-583"},"PeriodicalIF":0.0000,"publicationDate":"1994-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Preprints-American Chemical Society Division of Petroleum Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1201/9781482273540-19","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
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Abstract
This paper reports an experimental study of hydrodenitrogenation, at 330-350 °C and 50-150 atm total pressure, of carbazole on alumina-supported molybdenum nitride catalyst. The kinetics of C-N hydrogenolysis is analyzed to obtain rate expression for C-N hydrogenolysis which is a rate-determining step in equilibrium of the hydrogenation. Rate equations of the Langmuir-Hinshelwood type were compared with the rate dat using a non-linear leat-squares regression technique.
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