Intramolekular vernetzte poly(organosiloxan)partikel

Michael Geck, Bernward Deubzer, J. Weis
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引用次数: 3

Abstract

Intramolecularly crosslinked poly(organosiloxane) particles are prepared by means of emulsion polycondensation or emulsion polymerization of alkoxysilanes or cyclic organic siloxanes. Starting from these intramolecularly crosslinked poly(organosiloxane) particles, graft copolymers are obtained by free-radical emulsion polymerization of unsaturated olefinic monomers (e.g. acrylates, styrene) in the presence of (functionalized) organosiloxanes. Intramolecularly crosslinked poly(siloxane) particles and their graft copolymers are characterized by means of light scattering (in dispersion), electron microscopy and thermal analyses (DSC, DMTA)
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分子内部网络poly离子
采用烷氧硅烷或环有机硅氧烷乳液缩聚或乳液聚合的方法制备分子内交联聚有机硅氧烷颗粒。从这些分子内交联的聚(有机硅氧烷)颗粒开始,在(功能化的)有机硅氧烷存在下,通过自由基乳液聚合得到不饱和烯烃单体(如丙烯酸酯、苯乙烯)的接枝共聚物。分子内交联聚硅氧烷颗粒及其接枝共聚物通过光散射(分散)、电子显微镜和热分析(DSC, DMTA)进行了表征。
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