Effect of Mn substitution on acetone and ammonia sensing in CoFe2O4 nanoparticles

S. Sarkar, M. Bhatnagar
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Abstract

Mn has substituted part of Fe in cobalt ferrite (CoFe2O4) and resultant material has been abbreviated as CFMO (CoFe1.7Mn0.3O4). Chemical co-precipitation route has been followed for synthesis. X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive x-ray spectroscopy (EDX), I-V measurement were performed for sample characterization. The influence of Mn substitution was seen in lowering the operating temperature for both acetone and ammonia gas sensing with high response as well as very fast response and recovery timealong with temperature dependent selectivity.
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锰取代对CoFe2O4纳米颗粒中丙酮和氨传感的影响
在钴铁氧体(CoFe2O4)中,Mn取代了部分Fe,生成的材料简称为CFMO (CoFe1.7Mn0.3O4)。采用化学共沉淀法合成。采用x射线衍射(XRD)、扫描电镜(SEM)、能量色散x射线能谱(EDX)、I-V测量等方法对样品进行表征。Mn取代对丙酮气敏和氨气敏的影响是降低操作温度,具有高响应、快速响应和恢复时间以及温度依赖的选择性。
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