IT02. TiO2 nanoparticles loaded on graphene/carbon composite nanofibers by electrospinning for increased photocatalysis

Abstract

Graphene/carbon composite nanofibers (GCNFs) with attached TiO2 nanoparticles (TiO2-GCNF) were prepared, and their photocatalytic degradation ability under visible light irradiation was assessed. They were characterized using scanning and transmission electron microscopy, X-ray diffraction, Raman spectroscopy, X-ray photoelectron spectroscopy, and ultraviolet-visible diffuse spectroscopy. The results suggest that the presence of graphene embedded in the composite fibers prevents TiO2 particle agglomeration and aids the uniform dispersion of TiO2 on the fibers (Fig.1). In the photo-degradation of methylene blue, a significant increase in the reaction rate was observed with TiO2-GCNF materials under visible light. This increase is due to the high migration efficiency of photo-induced electrons and the inhibition of charge-carrier recombination due to the electronic interaction between TiO2 and graphene [1,2](Fig.2). The TiO2-GCNF materials could be used for multiple degradation cycles without a decrease in photocatalytic activity.